Journal of Crystal Growth, Vol.430, 41-45, 2015
Incorporation of air-cavity into sapphire substrate and its effect on GaN growth and optical properties
We propose a new GaN growth scheme using a cavity engineered sapphire substrate (CES), in which a patterned cavity array was formed on the sapphire surface. Amorphous alumina film was deposited by atomic layer deposition on a photoresist patterned sapphire substrate, and subsequent high temperature annealing resulted in the formation of a cavity array surrounded by a crystallized sapphire shell. During the GaN growth on CES, the GaN film filled up the space between the cavities and then grew laterally over them, leading to a completely coalesced pit free smooth surface. The incorporation of cavities was observed to reduce the stress in GaN film by 30%. The output power of a light emitting diode (LED) on CES at an input current of 20 mA was measured to be 22 Limes higher than that on a planar sapphire substrate. It was also found that the dominant peak wavelength of the LEDs on CES showed a red shift of 12 nm due to higher In incorporation associated with presumably lower surface temperature in the presence of air-cavity. (C) 2015 Elsevier B.V. All rights reserved.
Keywords:Stresses;Substrates;Metalorganic chemical vapor deposition;Solid phase epitaxy;Semiconducting III-V materials;Light emitting diodes