화학공학소재연구정보센터
Journal of Crystal Growth, Vol.434, 96-103, 2016
Influence of Al content on non-equilibrium solidification behavior of Ni-Al-Ta model single crystal alloys
The non-equilibrium solidification behaviors of five Ni-Al-Ta ternary model single crystal alloys with different Al contents were investigated by experimental analysis and theoretical calculation (by JMatPro) in this study. These model alloys respectively represented the gamma' phase with various volume fractions (100%, 75%, 50%, 25% and 0%) at 900 degrees C. It was found that with decreasing Al content, liquidus temperature of experimental alloys first decreased and then increased. Meanwhile, the solidification range showed a continued downward trend. In addition, with decreasing Al content, the primary phases of non-equilibrium solidified model alloys gradually transformed from gamma' phase to gamma phase, and the area fraction of which first decreased and then increased. Moreover, the interdendritic/intercellular precipitation of model alloys changed from beta phase (for 100% gamma') to (gamma+gamma')(Eutectic) (for 75% gamma'), (gamma+gamma')(Eutectic)+gamma' (for 50% gamma' and 25% gamma') and none interdendritic precipitation (for 0% gamma'), and the last stage non-equilibrium solidification sequence of model alloys was determined by the nominal Al content and different microsegregation behaviors of Al element. (C) 2015 Elsevier BY. All rights reserved.