화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.33, No.4, 1232-1238, April, 2016
DOI10.1007/s11814-015-0267-8  Export Citation
Efficient hydrolysis of cellulose over a magnetic lignin-derived solid acid catalyst in 1-butyl-3-methylimidazolium chloride
Lei Hu†, Zhen Wu, Jiaxing Xu, Shouyong Zhou, and Guodong Tang
  • Jiangsu Key Laboratory for Biomass-based Energy and Enzyme Technology, School of Chemistry and Chemical Engineering, Jiangsu Collaborative Innovation Center of Regional Modern Agriculture & Environmental Protection, Huaiyin Normal University, Huaian 223300, China
E-mail:
A green and efficient strategy for the hydrolysis of cellulose was developed by using a magnetic lignin-derived solid acid catalyst (MLC-SO3H) in the presence of ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl). The results indicated that reaction temperature, reaction time, catalyst loading and water content have a big influence on the yield of total reducing sugars (TRS). By optimizing these reaction parameters, 69.3% TRS yield was observed at 140 ℃ for 150 min with the addition of 40 wt% MLC-SO3H and 1 wt% water. More importantly, MLC-SO3H could be easily separated from the reaction mixture with an external magnet and could be repeatedly used five times without an obvious loss of catalytic activity, demonstrating that it possessed excellent recyclability. Furthermore, a plausible mechanism involving three consecutive processes of dissolution, adsorption and catalysis for the hydrolysis of cellulose in [BMIM]Cl over a catalyst of MLC-SO3H was also proposed.
Keywords:Cellulose;Hydrolysis;Total Reducing Sugars;Ionic Liquid;Magnetic Lignin-derived Solid Acid Catalyst
  1. Luterbacher JS, Rand JM, Alonso DM, Han J, Youngquist JT, Maravelias CT, Pfleger BF, Dumesic JA, Science, 343(6168), 277 (2014)
  2. Ni JP, Wang HL, Chen YY, She Z, Na HN, Zhu J, Bioresour. Technol., 137, 106 (2013)
  3. Vilcocq L, Castilho PC, Carvalheiro F, Duarte LC, ChemSusChem, 7, 1010 (2014)
  4. Pang JF, Wang AQ, Zheng MY, Zhang T, Chem. Commun., 46, 6935 (2010)
  5. Gonzalez-Rivera J, Galindo-Esquivel IR, Onor M, Bramanti E, Longo I, Ferrari C, Green Chem., 16, 1417 (2014)
  6. Fan JJ, De Bruyn M, Budarin VL, Gronnow MJ, Shuttleworth PS, Breeden S, Macquarrie DJ, Clark JH, J. Am. Chem. Soc., 135(32), 11728 (2013)
  7. Cantero DA, Bermejo MD, Cocero MJ, ChemSusChem, 8, 1026 (2015)
  8. Rinaldi R, Schuth F, ChemSusChem, 2, 1096 (2009)
  9. Cantero DA, Bermejo MD, Cocero M, Bioresour. Technol., 135, 697 (2013)
  10. Zhang QH, Benoit M, De Oliveira Vigier K, Barrault J, Jegou G, Philippe M, Jerome F, Green Chem., 15, 963 (2013)
  11. Hu L, Lin L, Wu Z, Zhou SY, Liu SJ, Appl. Catal. B: Environ., 174-175, 225 (2015)
  12. Gupta KM, Jiang JW, Chem. Eng. Sci., 121, 180 (2015)
  13. Wang H, Gurau G, Rogers RD, Chem. Soc. Rev., 41, 1519 (2012)
  14. Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)
  15. Swatloski RP, Spear SK, Holbrey JD, Rogers RD, J. Am. Chem. Soc., 124(18), 4974 (2002)
  16. Sun N, Rodriguez H, Rahman M, Rogers RD, Chem. Commun., 47, 1405 (2011)
  17. Zakzeski J, Grisel RJ, Smit AT, Weckhuysen BM, ChemSusChem, 5, 430 (2012)
  18. Yang ZZ, Huang RL, Qi W, Tong LP, Su RX, He ZM, Chem. Eng. J., 280, 90 (2015)
  19. Wu CY, Chen W, Zhong LX, Peng XW, Sun RC, Fang JJ, Zheng SB, J. Agric. Food Chem., 62, 7430 (2014)
  20. Freudenmann D, Wolf S, Wolff M, Feldmann C, Angew. Chem.-Int. Edit., 50, 11050 (2011)
  21. Zhang QH, Zhang SG, Deng YQ, Green Chem., 13, 2619 (2011)
  22. Startk A, Energy Environ. Sci., 4, 19 (2011)
  23. Wang JY, Zhou MD, Yuan YG, Zhang Q, Fang XC, Zang SL, Bioresour. Technol., 197, 42 (2015)
  24. Brandt A, Grasvik J, Hallett JP, Welton T, Green Chem., 15, 550 (2013)
  25. Remsing RC, Swatloski RP, Rogers RD, Moyna G, Chem. Commun., 12, 1271 (2006)
  26. Maki-Arvela P, Anugwom I, Virtanen P, Sjoholm R, Mikkola JP, Ind. Crop. Prod., 32, 175 (2010)
  27. Zhou LP, Yang XM, Xu JL, Shi MT, Wang F, Chen C, Xu J, Green Chem., 17, 1519 (2015)
  28. Parveen F, Patra T, Upadhyayula S, Carbohydr. Polym., 135, 280 (2016)
  29. Zhao XC, Wang J, Chen CM, Huang YQ, Wang AQ, Zhang T, Chem. Commun., 50, 3439 (2014)
  30. Shuai L, Pan XJ, Energy Environ. Sci., 5, 6889 (2012)
  31. Huang YB, Fu Y, Green Chem., 15, 1095 (2013)
  32. Rinaldi R, Palkovits R, Schuth F, Angew. Chem.-Int. Edit., 47, 8047 (2008)
  33. Gliozzi G, Innorta A, Mancini A, Bortolo R, Perego C, Ricci M, Cavani F, Appl. Catal. B: Environ., 145, 24 (2014)
  34. Cai HL, Li CZ, Wang AQ, Xu GL, Zhang T, Appl. Catal. B: Environ., 123-124, 333 (2012)
  35. Cheng MX, Shi T, Guan HY, Wang ST, Wang XH, Jiang ZJ, Appl. Catal. B: Environ., 107(1-2), 104 (2011)
  36. Takagaki A, Nishimura M, Nishimura S, Ebitani K, Chem. Lett., 40(10), 1195 (2011)
  37. Kobayashi H, Komanoya T, Hara K, Fukuoka A, ChemSusChem, 3, 440 (2010)
  38. Suganuma S, Nakajima K, Kitano M, Yamaguchi D, Kato H, Hayashi S, Hara M, J. Am. Chem. Soc., 130(38), 12787 (2008)
  39. Guo HX, Qi XH, Li LY, Smith RL, Bioresour. Technol., 116, 355 (2012)
  40. Onda A, Ochi T, Yanagisawa K, Green Chem., 10, 1033 (2008)
  41. Hu L, Tang X, Wu Z, Lin L, Xu JX, Xu N, Dai BL, Chem. Eng. J., 263, 299 (2015)
  42. Miller GL, Anal. Chem., 31, 426 (1959)
  43. Zhou LP, Liu Z, Shi MT, Du SS, Su YL, Yangm XM, Xu J, Carbohydr. Polym., 98, 146 (2013)
  44. Shen SG, Wang CY, Cai B, Li HM, Han Y, Wang T, Qin HF, Fuel, 113, 644 (2013)
  45. Liu M, Jia SG, Gong YY, Song CS, Guo XW, Ind. Eng. Chem. Res., 52(24), 8167 (2013)
  46. Qi XH, Lian YF, Yan LL, Smith RL, Catal. Commun., 57, 50 (2014)
  47. Hu SL, Smith TJ, Lou WY, Zong MH, J. Agric. Food Chem., 62, 1905 (2014)
  48. Xiong Y, Zhang ZH, Wang X, Liu B, Lin JT, Chem. Eng. J., 235, 349 (2014)
  49. Guo HX, Lian YF, Yan LL, Qi XH, Smith RL, Green Chem., 15, 2167 (2013)
  50. Kim SJ, Dwiatmoko AA, Choi JW, Suh YW, Suh DJ, Oh M, Bioresour. Technol., 101(21), 8273 (2010)
  51. Tian JA, Fan CY, Cheng MX, Wang XH, Chem. Eng. Technol., 34(3), 482 (2011)
  52. Lai DM, Deng L, Guo QX, Fu Y, Energy Environ. Sci., 4, 3552 (2011)