An innovative hydrophilic and anti-fouling coating material for application in membrane technology for wastewater treatment has been developed by polymerization of a polymerizable bicontinuous micro-emulsion (PBM) and used for surface modification of a commercial flat polyethersulfone (PES) membrane. The novel nanostructured coating has been produced using acryloyloxyundecyltriethylammonium bromide (AUTEAB) as a co-polymerizable surfactant, obtained through a synthetic method characterized by a lower cost and a higher reproducibility compared to other known polymerizable surfactants. The novel composite membranes have been characterized and compared with the uncoated PES membranes. Coated membranes resulted in a smoother surface and a higher hydrophilicity with respect to the uncoated ones, and showed a particular nano size channel like morphology making them highly resistant to the fouling phenomenon. The covalent anchorage of the surfactant on the membrane surface ensured the embedment of the molecule in the polymeric matrix avoiding its leaching and also leading the coated membranes to have significant antimicrobial activity, which is very important for reducing the biolouling phenomenon. All these aspects make the tailored coating material an ideal and efficient coating for modifications of commercial membrane surfaces, to be used in membrane processes in wastewater treatment. (C) 2015 Elsevier B.V. All rights reserved.