Experimental studies have been conducted to examine the strength and fracture behaviour of monofilament Nicalon SiC fibres with diameters ranging from 8 to 22 mu m. The effects of varying fibre diameter, flaw location and flaw population on the mechanical response of individual fibres were investigated by recourse to extensive fractographic analysis performed on fibres fractured under tensile loading. Results indicate that variations in fibre diameter influence the apparent fibre fracture toughness (K-1c), with higher K-1c values observed for decreasing fibre diameters. Observations also suggest that the location of the critical flaw may play a role in the fracture of Nicalon fibres. Tensile strength values are shown to increase as the normalized distance of the critical flaw from the fibre centre increases, while critical flaw population appears to be strongly dependent on location. The ratio of K-1c to geometry factor (Y) is observed to remain constant with varying flaw location. In addition to surface flaws, three distinct internal flaw populations are seen to cause fracture in Nicalon fibres. Based on these experimental findings, a statistical characterization of the strength of Nicalon fibres with varying diameters is presented in Part II of this paper.