화학공학소재연구정보센터
Journal of Non-Newtonian Fluid Mechanics, Vol.225, 86-93, 2015
Extrudate swell of HDPE melts: I. Experimental
The extrudate swell of high-density polyethylenes (HDPEs) in capillary flow is studied using an optical micrometer attached to the capillary rheometer. The effects of molecular structure, shear rate, die geometrical characteristics (entrance angle, length-to-diameter ratio and diameter) and temperature on extrudate swell are studied systematically and found to have a significant effect. In particular, extrudate swell increases with decrease of LID ratio and changes nonlinearly with entrance angle exhibiting different trends for concave (swell increases from 60 to 180) and convex (swell decreases from 180 to 300) angles. The swell also depends nonlinearly on die diameter, exhibiting a maximum at certain diameter. The molecular weight and its distribution (dominant) are also found to affect significantly the extrudate swell of HDPE. The ambient temperature is also an important parameter that is the higher its value, the higher the extrudate swell. Ultimate swell measurements have also been performed and the relative effects of stress relaxation and surface tension have been assessed independently through both experimentation and modeling. (C) 2015 Elsevier B.V. All rights reserved.