화학공학소재연구정보센터
Journal of Power Sources, Vol.289, 160-167, 2015
Electrical conductivity of PEMFC under loading
Conducting an experimental investigation, we show that the electrical conductivity a (Sm-1) of the gas diffusion layer (GDL) and bipolar plates in stainless steel foam (SSF), as the heart of a Proton Exchange Membrane Fuel Cell (PEMFC), depends in fact strongly on mechanical compression arising in an operating system. Thus, this mechanical compression significantly affects the current density and a; while it is not so far introduced in modelling and performance analysis. By mean of a developed metrology for this purpose and using Van der Pauw method, we studied, upon applied mechanical loads by varying the compression p, the electrical properties of different layers of a carbon cloth for GDL, of SSF, and, as in operating fuel cell, of the combination GDL + SSF in a sandwich form. A strong dependency is observed for each of these materials and their combination up to saturation for high enough p which is seen then to reduce the electrical resistance; while the number of layers has no influence. The obtained results are analysed in term of rate of increase of a with an interesting conclusion for their application. (C) 2015 Published by Elsevier B.V.