화학공학소재연구정보센터
Journal of Power Sources, Vol.305, 30-36, 2016
MnO2-Carbon nanotube composite for high-areal-density supercapacitors with high rate performance
Practical supercapacitor devices require high areal capacitance and area! power density, and thus demand high utilization of active material and good rate performance under high areal mass loading. However, ion transport in high-mass-loading electrodes can be a challenge, which leads to deteriorate specific capacitance and rate performance. In this paper, a well-dispersed porous MnO2-carbon nanotube (CNT) composite was prepared for use as a supercapacitor electrode material. The small MnO2 nano particles and porous CNT network facilitated fast electron/ion transfer kinetics in the electrode. With a mass loading as high as 6.4 mg cm(-2) on the electrode, the MnO2-CNT composite exhibited an excellent areal capacitance of 1.0 F cm(-2) at 0.2 A g(-1) (1.28 mA cm(-2)), with a retention of 77% even at a high current density of 20 A g(-1) (128 mA cm(-2)). The electrode exhibited a high power density of 45.2 kW kg(-1) (0.29 W cm(-2)) while maintaining a reasonable energy density of 16.7 Wh kg(-1) (106 mu Wh cm(-2)). No apparent fading was observed even after 3000 charge/discharge cycles at 1 A g(-1). This porous and evenly distributed MnO2-CNT composite has great potential for practical applications in supercapacitors. (C) 2015 Elsevier B.V. All rights reserved.