We fabricated two organopolymeric solar cells based on poly(N-vinyl carbazole) (PVK) mixed with metalloporphyrin/Alq₃ p-n junction system and evaporated metalloporphyrin/Alq₃ p-njunction system. 5,10,15,20-tetraphenylporphyrinatomagnesium (MgTPP) was used as a photogenerating dye and PVK was used as a electron transporter. Photovoltaic parameters (open circuit voltage (V_oc, short circuit current (J_sc), fill factor (FF) and conversion efficiency(η)) of ITO/PVK(MgTPP)/Alq₃/Al cell was calculated.