It has been long thought that Fe-N-C structure, where Fe is bonded with an electronegative heteroatom N, plays a key role as nonprecious Metal Catalyst for oxygen reduction reaction (ORR) in fuel tells. However, eledtrocatalytic activity of Fe bonded with electropositive heteroatom P has never been considered for ORR. Herein We report the electrocatalytic activity for ORR of new Fe-P-C.