화학공학소재연구정보센터
Langmuir, Vol.31, No.35, 9523-9526, 2015
Programming Tilting Angles in Shape Memory Polymer Janus Pillar Arrays with Unidirectional Wetting against the Tilting Direction
By coating a thin layer of metal, including gold and gold palladium alloy, of different thickness on the deformed shape memory polymer (SMP) pillars, we manipulate the degree of recovery of the SMP pillars. Pillars of different tilting angles were obtained as a result of balancing the strain recovery energy of the SMP pillars that favor the original straight state and the elastic energy of the metal layers that prefer the bent state. With this selective coating of a metal layer on the tilted pillars, we report a unique anisotropic liquid spreading behavior, where the water droplet is fully pinned in the direction of pillar tilting but advances in the reverse direction. This phenomenon is explained by the interplay of the surface chemistry and topography.