화학공학소재연구정보센터
Journal of Materials Science, Vol.34, No.8, 1783-1790, 1999
Evaluation of Si3N4 joints: bond strength and microstructure
Joining of pressurelessly sintered silicon nitride ceramics was carried out using adhesive slurries in the system Y-Si-Al-O-N in a nitriding atmosphere. The effects of bonding parameters, such as joining temperature (1450-1650 degrees C), applied pressure (0-5 MPa) and holding time (10-60 min), on the bond strength of joint were evaluated. A typical microstructure of the joint bonded with the optimum adhesive was investigated. The three point bend testing of joined samples with 3 x 4 x 36 mm(3) in dimension was employed to study the bond strength of joints. The results show that an optimum joining process was achieved by holding at 1600 degrees C for 30 min under an external pressure of 5 MPa and the maximum bond strength was 550 MPa, compared to 700 MPa of unbonded Si3N4 ceramic, using the adhesive having the Si3N4/Y2O3 + SiO2 + Al2O3) ratio of 0.39. The good bond strength is attributed to the similarity in microstructure and chemical composition between joint zone and ceramic substrate. The fracture modes were classified into two types according to the values of bond strength.