The energetic thermoplastic elastomers (ETPE) of glycidyl azide polymer with bonding functions were synthesized by using mixture of chain extenders including 1,4-butanediol and N-(2-cyanoethyl) diethanolamine. From FTIR results, the ability of ETPEs to form hydrogen bond weakened with the percentage of N-(2-cyanoethyl) diethanolamine increasing, which further lead to the decrease of maximum stress of ETPEs and increase of elongation at break. On the other hand, the interfacial interactions between solid ingredients and ETPEs were enhanced owing to the more -CN content. With the percentage of N-(2-cyanoethyl) diethanolamine increasing, two factors affect the adhesion between binder and fillers at the same time. The RDX/ETPE propellants were synthesized and the mechanical properties of them showed that the ETPE-50 with bonding functions can effectively prevent the dewetting, and then improve the mechanical properties of propellants. That is, when the percentage of N-(2-cyanoethyl) diethanolamine was 50 %, the synthesized ETPEs had not only binding function but also bonding interaction.