CuS/ZnS hexagonal plates were prepared through a solvothermal and subsequent cation-exchange reaction between the as-prepared precursor and Cu(NO3)(2) aqueous solution. The as-prepared CuS/ZnS composite photocatalysts were characterized by X-ray diffraction (XRD), inductively coupled plasma atomic emission spectrometry (ICP-AES), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), UV-Vis diffuse reflection spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectroscopy. The CuS/ZnS hexagonal plates exhibited efficient photocatalytic H-2 evolution activity from an aqueous Na2S and Na2SO3 solution without noble metal loading. The composite photocatalyst with 6% CuS content displayed the highest photocatalytic activity (1233.5 mu mol h(-1) g(-1)), which was almost 77 times higher than that of the mechanical mixture of CuS and ZnS. The enhanced visible light-induced photocatalytic activity is likely a result of the interfacial charge transfer of the CuS/ZnS heterojunction. Our proposed photocatalytic mechanism is supported by XPS and PL results. (C) 2015 Elsevier B.V. All rights reserved.