화학공학소재연구정보센터
Thin Solid Films, Vol.594, 238-244, 2015
Influence of the acetic acid concentration on the growth of zinc oxide thin films prepared by spray pyrolysis of aqueous solutions
Zinc oxide (ZnO) thin films were fabricated by ultrasonic spray pyrolysis using aqueous zinc acetate solutions. Acetic acidwas added as a stabilizing agent in the concentration range of 0.1 to 10 vol.% and its effects on themorphology and electrical and optical properties of the thin films were investigated. The increase of acetic acid in the solution led to more (001)-textured films and influenced the grain size and roughness. While this did not result in a significant difference in the optical transmission characteristics, a strong dependence in the electrical properties of the films could be observed. After illumination under a sun simulator with an AM 1.5G spectrum, the films presented a resistivity in the range of 0.2-9 Omega cm, with the lowest resistivity obtained for acetic acid concentration of 2 vol.%. The deposited films showed average optical transmittance higher than 80% (including the glass substrate) for wavelengths between 400 and 1000 nm. (C) 2015 Elsevier B.V. All rights reserved.