Molecular Crystals and Liquid Crystals, Vol.589, No.1, 154-161, 2014
The Effect of a Substrate on the Current-vs-Voltage Characteristics of Thin-Film Sandwich Structures Based on Buckminsterfullerene
We analyze the current-vs-voltage (J-V) characteristics of ITO/C-60/Al sandwich cells, where ITO is the double indium tin oxide, C-60 is the buckminsterfullerene and Al is the thermally evaporated top aluminum electrode. These cells were obtained on either glass/ITO or polyethyleneterephthalate/ITO substrates (or, optionally, on glass/ZnO substrates) in a parallel process under identical conditions. However, the J-V dependences in each series behave very differently. The results are discussed in terms of the migration of admixtures from a bulk substrate material toward the top metallic electrode, thus modifying the photovoltaic properties of cells.