In this study, we synthesized MPPG including the methylene-oxy group from polypropylene glycol (PPG) with the molecular weight (g/mol) of 200. Also UV curable resins were prepared from the mixture of polyurethane acrylate (PUA) oligomer which was synthesized with synthesized MPPG, TMPTA, HDDA, and HP-8 to investigate the possibility of its application for optical film materials. The T-g was higher for UAMP oligomer with MPPG as well as MPPG than that of PPG and UAP oligomer. The refractive index and the pencil hardness of UCM were higher than those of UC while the optical transmittances of UCM and UC were much the same.