Molecular Crystals and Liquid Crystals, Vol.616, No.1, 226-236, 2015
Synthesis, Characterization, Crystal Structure, and Hirshfeld Surface Analysis of 2-(2-Hydroxy-3-methoxyphenyl)-1-(4-methylphenyl)-4,5-diphenyl-1H-imidazo le
The substituted imidazole C29H24N2O2 was prepared via multicomponent reactions and the product crystallized using dimethylformamide. The structure of the compound was established by elemental analysis, FT-IR, thermogravimetric analysis, UV-Visible, and single-crystal X-ray diffraction. The molecule is crystallized in the tetragonal crystal system with the space group P4(3)2(1)2 and with unit cell parameters a = 12.226(1) angstrom, b = 12.226(1) angstrom, c = 31.807(3) angstrom, and Z = 8. The molecular and crystal structure of the title molecule is stabilized by intramolecular interactions, O-H center dot center dot center dot N and C-H center dot center dot center dot N, and intermolecular interaction, C-H center dot center dot center dot O.
Keywords:Crystallization;crystal structure;FTIR spectrum;hirshfeld surface;imidazole;intermolecular interactions;multicomponent reaction;thermo gram