Turkish Journal of Chemistry, Vol.39, No.4, 789-800, 2015
Microwave-assisted regioselective [1,3] -dipolar cycloaddition of 3-methyl-2-(substitutedbenzylidene)-5-oxopyrazolidin-2-ium-1-ides to benzothiophene 1,1-dioxide
A series of pyrazolidinium ylides was reacted with benzothiophene 1,1-dioxide to afford (3R,5S,5aS,10bS)-3-methyl-5-substitutedphenyl-2,3,5,5a-tetrahydrobenzo [4,5] thieno [3,2-c] pyrazolo [1,2-a]pyrazol-1 (10bH)-one 6,6-dioxides under microwave irradiation and their structures were identified by means of spectral/physical characteristics including X-ray diffraction data and HRMS measurements.
Keywords:Microwave-assisted synthesis;pyrazolidinium;ylide;1,3-dipolar cycloaddition;benzothiophene dioxide