화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.41, No.8, 4792-4798, 2016
Low-temperature co-firing process of solid oxide fuel cells by a trace of copper
8 mol % yttria stabilized zirconia (8 YSZ) is widely used as an electrolyte material for solid oxide fuel cells (SOFCs) at high temperatures, but its poor sinterability causes complications of the cell fabrication processes, increasing manufacturing costs significantly. In this study, a low-temperature co-firing process for the YSZ-based SOFCs is developed by adding the small amount of Cu to each of YSZ electrolytes and anodes. The cells are successfully fabricated without any distortions or cracks. The cell is about 1.011 V at 850 degrees C in open circuit voltage (OCV), which is reasonable despite of the co-firing process even at 1250 degrees C. The maximum power density is 0.71 W cm(-2) at 850 degrees C, which has similar performance of a conventional cell fabricated by multi-step process. Overall, the co-firing process using Cu can become promising for cost-effective fabrication process of the SOFCs except the problems related to the cathode. Copyright (c) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.