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International Journal of Molecular Sciences, Vol.3, No.8, 914-930, 2002
Self-energy Effects on Nuclear Magnetic Resonance Parameters within Quantum Electrodynamics Perturbation Theory
A theory for the calculation of self-energy corrections to the nuclear magnetic parameters is given in this paper. It is based on the S-matrix formulation of bound-state quantum electrodynamics (QED). Explicit expressions for the various terms of the S-matrix are given. The interpretation of the self-energy, one-and two-vertex terms and some perspective for possible future developments are discussed.
Keywords:NMR parameters;Quantum Electrodynamics;S-matrix theory;Self-energy correction;Dirac-Fock perturbation theory