화학공학소재연구정보센터
Separation and Purification Technology, Vol.144, 107-113, 2015
Synthesis of magnetically separable N, La-doped TiO2 with enhanced photocatalytic activity
A magnetically separable nitrogen and lanthanum co-doped photocatalyst gamma-Fe2O3@SiO2@N,La-TiO2 (FST) with a typical superparamagnetic property was prepared by an effective three-step approach. Specifically, the preformed monodisperse gamma-Fe2O3 nanoparticles were used as templates for directing the sequential deposition of SiO2 layer by modified Stober method and subsequent N,La-TiO2 layer by hydrothermal method. During the hydrothermal assisted TiO2 deposition, the interior black Fe3O4 nanoparticles were converted into dark-brown gamma-Fe2O3 nanoparticles. EST showed a ternary structure with a core of gamma-Fe2O3, a SiO2 mesosphere and a N,La-TiO2 (anatase) crust. SiO2 layer can prevent effectively the transfer of charges from TiO2 to gamma-Fe2O3, which avoids electrons and holes recombination at the interface. SiO2 inter-layer is also a good adsorbent for dye molecules, FST showed higher photocatalytic activity than gamma-Fe2O3@N,La-TiO2 (FT). FST is photoactive under both UV and visible light irradiation and can be easily separated from a slurry in photoreactor by the application of an external magnetic field. (c) 2015 Elsevier B.V. All rights reserved.