Improved synthesis of copper oxide nanosheets and its application in development of supercapacitor and antimicrobial agents

Surendra Shinde; Haridas Dhaygude; Dae-Young Kim; Gajanan Ghodake; Prashant Bhagwat; Padma Dandge; Vijay Fulari

Journal of Industrial and Engineering Chemistry, Vol.36, 116-120, April, 2016

DOI10.1016/j.jiec.2016.01.038 Export Citation

Improved synthesis of copper oxide nanosheets and its application in development of supercapacitor and antimicrobial agents

Surendra Shinde, Haridas Dhaygude, Dae-Young Kim¹, Gajanan Ghodake^{1, †}, Prashant Bhagwat², Padma Dandge³, and Vijay Fulari^†

Holography and Materials Research Laboratory, Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra, India
¹College of Life Science and Biotechnology, Department of Biological and Environmental Science, Dongguk University, 32, Ilsandong-gu, Goyang-si, Gyeonggi-do, South Korea
²Department of Microbiology, Shivaji University, Kolhapur 416 004, Maharashtra, India
³Department of Biochemistry, Shivaji University, Kolhapur 416 004, Maharashtra, India

E-mail:,

Copper oxide (CuO) nanosheets (NSs) have been synthesized using improved chemical bath deposition (CBD) method and used as energy materials in supercapacitor devices. The quality of CuO-NSs were investigated using different techniques such as, cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy. The structure, composition, and morphology of CuO-NSs were examined by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersion spectrum (EDS). CuO-NSs device exhibited maximum specific capacitance about 564 Fg-1 at 5 mV/s. Antibacterial properties of CuO-NSs with Bacillus subtilis and Salmonella typhimurium have shown promising prospects for the development of antibacterial agents.

Keywords:Copper oxide;Nanosheets;CuO-NSs;Supercapacitor;Antibacterial agents

[References]

Wu J, Xue D, Cryst. Eng. Comm., 13, 1966 (2011)
Zhang Y, Sun C, Lu P, Li K, Song S, Xue D, Cryst. Eng. Comm., 14, 5892 (2012)
Park JC, Kim J, Kwon H, Song H, Adv. Mater., 21(7), 803 (2009)
Liu J, Xia H, Xue DF, Lu L, J. Am. Chem. Soc., 131(34), 12086 (2009)
Liu J, Xue DF, Adv. Mater., 20(13), 2622 (2008)
Katwal R, Kaur H, Sharma G, Naushad M, Pathania D, J. Ind. Eng. Chem., 31, 173 (2015)
Barreca D, Carraro G, Gasparotto A, Maccato C, Yusta MC, Camer JLG, Morales J, Sada C, Sanchez L, ACS Appl. Mater. Interfaces, 4, 3610 (2012)
Liu J, Xia H, Lu L, Xue D, J. Mater. Chem., 20, 1506 (2010)
Chen K, Xue D, Cryst. Eng. Comm., 14, 8068 (2012)
Xu J, Xue D, Acta Mater., 55, 2397 (2007)
Chen K, Xue D, Nanosci. Nanotechnol. Lett., 4, 1 (2012)
Chen K, Song S, Xue D, Cryst. Eng. Comm., 15, 144 (2013)
Kang W, Liu F, Su Y, Wang D, Shen Q, Cryst. Eng. Comm., 13, 4174 (2011)
Ko S, Lee JI, Yang HS, Park S, Jeong U, Adv. Mater., 24(32), 4451 (2012)
Ghaedi M, Ghaedi AM, Hossainpour M, Ansari A, Habibi MH, Asghari AR, J. Ind. Eng. Chem., 20(4), 1641 (2014)
Jibril BY, Atta AY, Al-Waheibi YM, Al-Waheibi TK, J. Ind. Eng. Chem., 19(6), 1800 (2013)
Kim DW, Rhee KY, Park SJ, J. Alloy. Compd., 530, 6 (2012)
Wang GL, Huang JC, Chen SL, Gao YY, Cao DX, J. Power Sources, 196(13), 5756 (2011)
Dubal DP, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD, J. Alloy. Compd., 492, 26 (2010)
Shinde SK, Dubal DP, Ghodake GS, Fulari VJ, RSC Adv., 5, 4443 (2015)
Shinde SK, Dubal DP, Ghodake GS, Kim DY, Fulari VJ, J. Electroanal. Chem., 732, 80 (2014)
Christy AJ, Nehru LC, Umadevi M, Powder Technol., 235, 783 (2013)
Ekthammathat N, Thongtem T, Thongtem S, Appl. Surf. Sci., 277, 211 (2013)
Foster HA, Sheel DW, Sheel P, Evans P, Varghese S, Rutschke N, Yates HM, J. Photochem. Photobiol. A-Chem., 216, 283 (2010)
Sivaraj R, Rahman PK, Rajiv P, Salam HA, Venckatesh R, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 133, 178 (2014)
Ren G, Hu D, Cheng EWC, Vargas-Reus MA, Reip P, Allaker RP, Int. J. Antimicrob. Agents, 33, 587 (2009)
Patterson AL, Phys. Rev., 56, 978 (1939)
Ahamed M, Alhadlaq HA, Khan MAM, Karuppiah P, Al-Dhabi NA, J. Nanomater., 14, 4 (2014)
Pang H, Ma Y, Li G, Chen J, Zhang J, Zheng H, Du W, J. Chem. Soc.-Dalton Trans., 41, 13284 (2012)
Dubal DP, Lee SH, Kim JG, Kim WB, Lokhande CD, J. Mater. Chem., 22, 3044 (2012)
Gund GS, Dubal DP, Jambhure SB, Shinde SS, Lokhande CD, J. Mater. Chem. A, 1, 4793 (2013)
Dubal DP, Gund GS, Lokhande CD, Holze R, ACS Appl. Mater. Interfaces, 5, 2446 (2013)
Nathan P, Law EJ, Murphy DF, Burns, 5, 177 (1978)
Hans M, Erbe A, Mathews S, Chen Y, Solioz M, Mucklich F, Langmuir, 29(52), 16160 (2013)
Ghodake G, Limb SR, Lee DS, Colloids Surf. B: Biointerfaces, 108, 147 (2013)

[Referenced By]

[1] Wu J, Xue D, Cryst. Eng. Comm., 13, 1966 (2011)

[2] Zhang Y, Sun C, Lu P, Li K, Song S, Xue D, Cryst. Eng. Comm., 14, 5892 (2012)

[3] Park JC, Kim J, Kwon H, Song H, Adv. Mater., 21(7), 803 (2009)

[4] Liu J, Xia H, Xue DF, Lu L, J. Am. Chem. Soc., 131(34), 12086 (2009)

[5] Liu J, Xue DF, Adv. Mater., 20(13), 2622 (2008)

[6] Katwal R, Kaur H, Sharma G, Naushad M, Pathania D, J. Ind. Eng. Chem., 31, 173 (2015)

[7] Barreca D, Carraro G, Gasparotto A, Maccato C, Yusta MC, Camer JLG, Morales J, Sada C, Sanchez L, ACS Appl. Mater. Interfaces, 4, 3610 (2012)

[8] Liu J, Xia H, Lu L, Xue D, J. Mater. Chem., 20, 1506 (2010)

[9] Chen K, Xue D, Cryst. Eng. Comm., 14, 8068 (2012)

[10] Xu J, Xue D, Acta Mater., 55, 2397 (2007)

[11] Chen K, Xue D, Nanosci. Nanotechnol. Lett., 4, 1 (2012)

[12] Chen K, Song S, Xue D, Cryst. Eng. Comm., 15, 144 (2013)

[13] Kang W, Liu F, Su Y, Wang D, Shen Q, Cryst. Eng. Comm., 13, 4174 (2011)

[14] Ko S, Lee JI, Yang HS, Park S, Jeong U, Adv. Mater., 24(32), 4451 (2012)

[15] Ghaedi M, Ghaedi AM, Hossainpour M, Ansari A, Habibi MH, Asghari AR, J. Ind. Eng. Chem., 20(4), 1641 (2014)

[16] Jibril BY, Atta AY, Al-Waheibi YM, Al-Waheibi TK, J. Ind. Eng. Chem., 19(6), 1800 (2013)

[17] Kim DW, Rhee KY, Park SJ, J. Alloy. Compd., 530, 6 (2012)

[18] Wang GL, Huang JC, Chen SL, Gao YY, Cao DX, J. Power Sources, 196(13), 5756 (2011)

[19] Dubal DP, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD, J. Alloy. Compd., 492, 26 (2010)

[20] Shinde SK, Dubal DP, Ghodake GS, Fulari VJ, RSC Adv., 5, 4443 (2015)

[21] Shinde SK, Dubal DP, Ghodake GS, Kim DY, Fulari VJ, J. Electroanal. Chem., 732, 80 (2014)

[22] Christy AJ, Nehru LC, Umadevi M, Powder Technol., 235, 783 (2013)

[23] Ekthammathat N, Thongtem T, Thongtem S, Appl. Surf. Sci., 277, 211 (2013)

[24] Foster HA, Sheel DW, Sheel P, Evans P, Varghese S, Rutschke N, Yates HM, J. Photochem. Photobiol. A-Chem., 216, 283 (2010)

[25] Sivaraj R, Rahman PK, Rajiv P, Salam HA, Venckatesh R, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 133, 178 (2014)

[26] Ren G, Hu D, Cheng EWC, Vargas-Reus MA, Reip P, Allaker RP, Int. J. Antimicrob. Agents, 33, 587 (2009)

[27] Patterson AL, Phys. Rev., 56, 978 (1939)

[28] Ahamed M, Alhadlaq HA, Khan MAM, Karuppiah P, Al-Dhabi NA, J. Nanomater., 14, 4 (2014)

[29] Pang H, Ma Y, Li G, Chen J, Zhang J, Zheng H, Du W, J. Chem. Soc.-Dalton Trans., 41, 13284 (2012)

[30] Dubal DP, Lee SH, Kim JG, Kim WB, Lokhande CD, J. Mater. Chem., 22, 3044 (2012)

[31] Gund GS, Dubal DP, Jambhure SB, Shinde SS, Lokhande CD, J. Mater. Chem. A, 1, 4793 (2013)

[32] Dubal DP, Gund GS, Lokhande CD, Holze R, ACS Appl. Mater. Interfaces, 5, 2446 (2013)

[33] Nathan P, Law EJ, Murphy DF, Burns, 5, 177 (1978)

[34] Hans M, Erbe A, Mathews S, Chen Y, Solioz M, Mucklich F, Langmuir, 29(52), 16160 (2013)

[35] Ghodake G, Limb SR, Lee DS, Colloids Surf. B: Biointerfaces, 108, 147 (2013)