화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.36, 255-262, April, 2016
DOI10.1016/j.jiec.2016.02.010  Export Citation
Layered double hydroxides/oxidized carbon nanotube nanocomposites for CO2 capture
Junya Wang, Liang Huang, Qianwen Zheng, Yaqian Qiao, and Qiang Wang†
  • College of Environmental Science and Engineering, Beijing Forestry University, 35 Qinghua East Road, Haidian District, Beijing 100083, PR China
E-mail:
A systematic investigation on the influence of synthesis method and chemical composition of LDH/oxidized carbon nanotube (LDH/OCNT) nanocomposites on their CO2 capture performance were performed. Three LDH/OCNT nanocomposites were prepared using two methods: “electrostatic self-assembly” and “direct co-precipitation”. All LDH/OCNT nanocomposites were thoroughly characterized. The isothermal CO2 adsorption at different temperatures (60-400 °C) and adsorption/desorption cycling tests were conducted. Both the CO2 adsorption capacity and the multi-cycle stability of LDH derived adsorbents were improved by the introduction of OCNT. In particular, the absolute CO2 capture capacity of Mg-Al-NO3 LDH was increased by more than twice by adding 9.1 wt% OCNT.
Keywords:CO2 adsorbent;Hydrotalcite;Sorption enhanced water gas shift;Synthesis method;Stability
  1. Mikkelsen M, Jørgensn M, Krebs FC, Energy Environ. Sci., 3, 43 (2010)
  2. Wang J, Huang L, Yang R, Zhang Z, Wu J, Gao Y, Wang Q, O‘Hare D, Zhong Z, Energy Environ. Sci., 7, 3478 (2014)
  3. Zhang Z, Wang J, Huang L, Gao Y, Umar A, Huang Z, Wang Q, Sci. Adv. Mater., 6, 1 (2014)
  4. Lee SY, Park SJ, J. Ind. Eng. Chem., 23, 1 (2015)
  5. Adelodun AA, Lim YH, Jo YM, J. Ind. Eng. Chem., 20(4), 2130 (2014)
  6. Lee YC, Lee SM, Hong WG, Huh YS, Park SY, Lee SC, Lee J, Lee JB, Lee HU, Kim HJ, J. Ind. Eng. Chem., 23, 16 (2015)
  7. Cao Y, Zhao Y, Lv Z, Song F, Zhong Q, J. Ind. Eng. Chem., 27, 102 (2015)
  8. Cho Y, Lee JY, Bokare AD, Kwon SB, Park DS, Jung WS, Choi JS, Yang YM, Lee JY, Choi W, J. Ind. Eng. Chem., 22, 350 (2015)
  9. Rabiee H, Alsadat SM, Soltanieh M, Mousavi SA, Ghadimi A, J. Ind. Eng. Chem., 27, 223 (2015)
  10. Huang L, Wang J, Gao Y, Qiao Y, Zheng Q, Guo Z, Zhao Y, O‘Hare D, Wang Q, J. Mater. Chem. A, 2, 18454 (2014)
  11. Rusten HK, Ochoa-Fernandez E, Lindborg H, Chen D, Jakobsen HA, Ind. Eng. Chem. Res., 46(25), 8729 (2007)
  12. Ortiz AL, Harrison DP, Ind. Eng. Chem. Res., 40(23), 5102 (2001)
  13. Wang Q, O'Hare D, Chem. Rev., 112(7), 4124 (2012)
  14. Reddy MKR, Xu ZP, Lu GQ, da Costa JCD, Ind. Eng. Chem. Res., 45(22), 7504 (2006)
  15. Lwin Y, Abdullah F, J. Therm. Anal. Calorim., 97, 885 (2009)
  16. Wang Q, Tay HH, Ng DJW, Chen L, Liu Y, Chang J, Zhong Z, Luo J, Borgna A, ChemSusChem, 3, 965 (2010)
  17. Wang Q, Tay HH, Zhong Z, Luo J, Borgna A, Energy Environ. Sci., 5, 7526 (2012)
  18. Wang Q, Wu ZH, Tay HH, Chen LW, Liu Y, Chang J, Zhong ZY, Luo JZ, Borgna A, Catal. Today, 164(1), 198 (2011)
  19. Hutson ND, Attwood BC, Adsorption, 14, 781 (2008)
  20. Sharma U, Tyagi B, Jasra RV, Ind. Eng. Chem. Res., 47(23), 9588 (2008)
  21. Reddy MKR, Xu ZP, Lu GQ, da Costa JCD, Ind. Eng. Chem. Res., 47(8), 2630 (2008)
  22. Dadwhal M, Kim TW, Sahimi M, Tsotsis TT, Ind. Eng. Chem. Res., 47(16), 6150 (2008)
  23. Wang Q, Tay HH, Guo Z, Chen L, Liu Y, Chang J, Zhong Z, Luo J, Borgna A, Appl. Clay Sci., 55, 18 (2012)
  24. Oliveira ELG, Grande CA, Rodrigues AE, Sep. Purif. Technol., 62(1), 137 (2008)
  25. Ebner AD, Reynolds SP, Ritter JA, Ind. Eng. Chem. Res., 45(18), 6387 (2006)
  26. Lee KB, Verdooren A, Caram HS, Sircar S, J. Colloid Interface Sci., 308(1), 30 (2007)
  27. Walspurger S, Boels L, Cobden PD, Elzinga GD, Haije WG, van den Brink RW, ChemSusChem, 1, 643 (2008)
  28. Wang Q, Tay HH, Chen L, Liu Y, Chang J, Zhong Z, Luo J, Borgna A, J. Nanoeng. Nanomanuf., 1, 298 (2011)
  29. Wu YJ, Li P, Yu JG, Cunha AF, Rodrigues AE, Chem. Eng. Technol., 36(4), 567 (2013)
  30. Meis NNAH, Bitter JH, de Jong KP, Ind. Eng. Chem. Res., 49(3), 1229 (2010)
  31. Garcia-Gallastegui A, Iruretagoyena D, Mokhtar M, Asiri AM, Basahel SN, Al-Thabaiti SA, Alyoubi AO, Chadwick D, Shaffer MSP, Chem. Mater., 24, 4531 (2012)
  32. Garcia-Gallastegui A, Iruretagoyena D, Mokhtar M, Asiri AM, Basahel SN, Al-Thabaiti SA, Alyoubi AO, Chadwickd D, Shaffer MSP, J. Mater. Chem. A, 22, 13932 (2012)
  33. Reynolds SP, Ebner AD, Ritter JA, Ind. Eng. Chem. Res., 45(12), 4278 (2006)
  34. Wang J, Mei X, Huang L, Zheng Q, Qiao Y, Zang K, Mao S, Yang R, Zhang Z, Gao Y, Guo Z, Huang Z, Wang Q, J. Energy Chem., 24, 127 (2015)
  35. Wang J, Huang L, Gao Y, Yang R, Zhang Z, Guo Z, Wang Q, Chem. Commun., 50, 10130 (2014)
  36. Huang S, Peng H, Tjiu WW, Yang Z, Zhu H, Tang T, Liu T, J. Phys. Chem. B, 114 (2010)
  37. Yang B, Yang ZH, Wang RJ, Wang TT, Electrochim. Acta, 111, 581 (2013)
  38. Yang W, Gao Z, Wang J, Ma J, Zhang M, Liu L, ACS Appl. Mater. Interfaces, 5, 5443 (2013)
  39. Gunjakar JL, Kim IY, Lee JM, Lee NS, Hwang SJ, Energy Environ. Sci., 6, 1008 (2013)
  40. Xing YC, Li L, Chusuei CC, Hull RV, Langmuir, 21(9), 4185 (2005)
  41. Wang H, Xiang X, Li F, J. Mater. Chem., 20, 3944 (2010)
  42. Huang Z, Wu P, Gong B, Fang Y, Zhu N, J. Mater. Chem., 2, 5534 (2014)
  43. Ding Y, Alpay E, Chem. Eng. Sci., 55(18), 3929 (2000)
  44. Ding Y, Alpay E, Chem. Eng. Sci., 55(17), 3461 (2000)