Macromolecular Research, Vol.24, No.4, 366-370, April, 2016
Morphology controlled synthesis of octahedral covalent imine frameworks through acid modulated aldehyde-amine polycondensation
E-mail:
The past decades have witnessed significant advance in the synthesis of covalent organic frameworks (COFs), however, their formation and morphology revolution mechanism have been rarely reported. Here, through an acid modulated dynamic covalent chemistry approach, pure and uniform micro-octahedral covalent imine frameworks were obtained for the first time. Formation mechanism based on the stacking of initially formed two-dimensional nanoplates followed by surface smoothing enabled by the dynamic nature of imine bonding was proposed. Furthermore, we revealed for the first time that nonstoichiometric method can be applied to the synthesis of covalent organic frameworks. Thus we provide novel strategy for the morphology control COFs which will surely facilitate their application in energy-related area.
Keywords:covalent organic frameworks;dynamic covalent chemistry;morphology control;solvothermal synthesis
- Cote AP, Benin AI, Ockwig NW, O’Keeffe M, Matzger J, Yaghi OM, Science, 310, 1166 (2005)
- El-Kaderi HM, Hunt JR, Mendoza-Cortes JL, Cote AP, Taylor RE, O’Keeffe M, Yaghi OM, Science, 316, 268 (2007)
- Trewin A, Cooper AI, Angew. Chem.-Int. Edit., 49, 1533 (2010)
- Feng X, Ding X, Jiang D, Chem. Soc. Rev., 41, 6010 (2012)
- Ding SY, Wang W, Chem. Soc. Rev., 42, 548 (2013)
- Tsyurupa MP, Davankov VA, React. Funct. Polym., 53(2-3), 193 (2002)
- Wood CD, Tan B, Trewin A, Niu H, Bradshaw D, Rosseinsky MJ, Khimyak YZ, Campbell NL, Kirk R, Stoeckel E, Cooper AI, Chem. Mater., 19, 2034 (2007)
- Germain J, Frechet JMJ, Svec F, J. Mater. Chem., 17, 4989 (2007)
- Cooper AI, Adv. Mater., 21(12), 1291 (2009)
- Jiang JX, Su F, Trewin A, Wood CD, Campbell NL, Niu H, Dickinson C, Ganin AY, Rosseinsky MJ, Khimyak YZ, Cooper AI, Angew. Chem.-Int. Edit., 46, 8574 (2007)
- Gomes R, Bhanja P, Bhaumik A, Chem. Commun., 51, 10050 (2015)
- Bhunia MK, Das SK, Pachfule P, Banerjee R, Bhaumik A, J. Chem. Soc.-Dalton Trans., 41, 1304 (2012)
- Uribe-Romo FJ, Doonan CJ, Furukawa H, Oisaki K, Yaghi OM, J. Am. Chem. Soc., 133(30), 11478 (2011)
- Uribe-Romo FJ, Hunt JR, Furukawa H, Klock C, O'Keeffe M, Yaghi OM, J. Am. Chem. Soc., 131(13), 4570 (2009)
- Neti V, Wu XF, Deng SG, J. Polym. Sci. A: Polym. Chem., 4, 4566 (2013)
- Kuhn P, Antonietti M, Thomas A, Angew. Chem.-Int. Edit., 47, 3450 (2008)
- Kuhn P, Forget A, Su DS, Thomas A, Antonietti M, J. Am. Chem. Soc., 130(40), 13333 (2008)
- Kuhn P, Thomas A, Antonietti M, Macromolecules, 42(1), 319 (2009)
- Chen X, Addicoat M, Irle S, Nagai A, Jiang DL, J. Am. Chem. Soc., 135(2), 546 (2013)
- Wan S, Guo J, Kim J, Ihee H, Jiang DL, Angew. Chem.-Int. Edit., 47, 8826 (2008)
- Feng XA, Chen L, Dong YP, Jiang DL, Chem. Commun., 47, 1979 (2011)
- Yan YZ, Chen L, Dai HJ, Chen ZH, Li X, Liu XK, Polymer, 53(8), 1611 (2012)
- Chen L, Chen ZH, Li X, Huang W, Li XJ, Liu XK, Polymer, 54(7), 1739 (2013)
- Huang W, Jiang Y, Li X, Li XJ, Wang JY, Wu Q, Liu XK, ACS Appl. Mater. Interfaces, 5, 8845 (2013)
- Nishiyabu R, Teraoka S, Matsushima Y, Kubo Y, Chempluschem, 77, 201 (2012)
- Wan S, Gandara F, Asano A, Furukawa H, Saeki A, Dey S, Liao L, Ambrogio M, Botros Y, Duan XF, Seki S, Stoddart JF, Yaghi OM, Chem. Mater., 23, 4094 (2011)
- Wakabayashi K, Kohama SI, Yamazaki S, Kimura K, Macromolecules, 41(4), 1168 (2008)