화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.149, 60-65, 2016
Metal foam embedded in SEBS/paraffin/HDPE form-stable PCMs for thermal energy storage
The objective of this study is to overcome the leakage and low thermal conductivity problems of paraffin as PCMs (phase change materials) for thermal energy storage by impregnating SEBS/paraffin/HDPE FSPCMs (form-stable phase change materials) into metal foam. The form-stable composites were prepared by absorbing paraffin into the network of powder-like styrene-b-(ethylene-co-butylene)-b-styrene (SEBS) triblock copolymer and covering high-density polyethylene (HDPE) on pre-prepared SEBS/paraffin mixture. The composites were characterized by using differential scanning calorimetry (DSC), Scanning electron microscope (SEM), Fourier Transform Infrared Spectrometer (FT-IR), X-Ray Diffraction (XRD) and Hot disk. Paraffin leakage was investigated by accelerated degradation test at 80 degrees C. The melting temperature and latent heat of the composites were determined as 50.56 degrees C and 151.6 J/g, respectively. FT-IR results revealed good chemical compatibility among paraffin, SEBS and HDPE. SEM images and XRD test results demonstrated that the paraffin had uniformly dispersed into SEBS. This composite was testified able to keep paraffin from seepage with only 2.39 wt% of paraffin loss after 50 thermal cycles test (150 h). In addition, the thermal conductivity of SEBS/paraffin/HDPE was 0.272 W/m K, which was increased up to 2.142 W/m K when copper foam was embedded in the composite. (C) 2016 Elsevier B.V. All rights reserved.