화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.88, 22-29, 2015
Phase behavior of ionic liquids 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imides with halogenated benzenes
(Liquid + liquid) miscibility temperatures as a function of composition have been determined experimentally for the binary systems formed by imidazolium based ionic liquids with bis(trifluoromethylsulfonyl) imide ([CnMIM][NTf2]: n = 3 to 10) with fluorobenzene, chlorobenzene, bromobenzene, iodobenzene and 1,2-dichlorobenzene. In addition, the phase diagrams for deuterated chlorobenzene, bromobenzene and 1,2-dichlorobenzene have been obtained. All the measured systems show the limited miscibility with the upper critical solution temperature behavior. Similarly to the other systems with the imidazolium cation the increase of the alkyl chain length in this cation improves the miscibility. The impact of the halogenobenzene is also very visible. The miscibility is improving in the order: iodobenzene < bromobenzene < chlorobenzene < fluorobenzene. This arrangement corresponds to the decreasing molar volume of the substituted benzenes. The disubstituted chlorobenzene is a better solvent for ionic liquids than chlorobenzene. The replacement of hydrogen for deuterium in halogenobenzenes in all cases improves the miscibility and the isotope shifts of the UCSTs are very large. (C) 2015 Elsevier Ltd. All rights reserved.