화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.37, 340-346, May, 2016
DOI10.1016/j.jiec.2016.03.043  Export Citation
Fabrication of ZnWO4-CdS heterostructure photocatalysts for visible light induced degradation of ciprofloxacin antibiotics
Pengwei Huo1, 2, †, Yanfeng Tang1, 3, Mingjun Zhou1, 3, Jinze Li1, 3, Zhefei Ye1, 3, Changchang Ma1, 3, Longbao Yu1, 3, and Yongsheng Yan1, 2, †
  • 1School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China
  • 2Institute of Green Chemistry and Chemical Technology, Jiangs University, Zhenjiang 212013, PR China
  • 3, China
E-mail:,
ZnWO4-CdS heterostructure photocatalysts have been successfully synthesized by hydrothermal method with assembling CdS on the surface of ZnWO4. The obtained composite photocatalysts were characterized by X-ray diffraction, transmission electron microscopy, Raman, thermo-gravimetric analysis, UV-vis diffuse reflectance spectroscopy, photoluminescence and photocurrent measurement. The results show that the interface between ZnWO4 and CdS is well formed, and the CdS nanoparticles are uniformly distributed onto ZnWO4 nanorods which could facilitate charge transfer and reduce recombination of photo-generated electrons and holes. Compared with pure ZnWO4 and CdS, the asprepared heterostructure photocatalysts exhibit excellent photostability and photodegradation ability of ciprofloxacin (CIP) under visible light irradiation.
Keywords:ZnWO4;CdS;Heterostructure;Photocatalytic degradation;Ciprofloxacin
  1. Kwon KW, Shim M, J. Am. Chem. Soc., 127(29), 10269 (2005)
  2. Qu J, Yin YX, Wang YQ, Yan Y, Guo YG, Song WG, ACS Appl. Mater. Interfaces, 5, 3932 (2013)
  3. Dey S, Ricciardo RA, Cuthbert HL, Woodward PM, Inorg. Chem., 53(9), 4394 (2014)
  4. Khairy M, J. Alloy. Compd., 608, 283 (2014)
  5. Zhang CL, Zhang HL, Zhang KY, Li XY, Leng Q, Hu CG, ACS Appl. Mater. Interfaces, 6, 14423 (2014)
  6. Atuchin VV, Galashov EN, Kozhukhov AS, Pokrovsky LD, Shlegel VN, J. Cryst. Growth, 318(1), 1147 (2011)
  7. Atuchin VV, Galashov EN, Khyzhun OY, Kozhukhov AS, Pokrovsky LD, Shlegel VN, Cryst. Growth Des., 11, 2479 (2011)
  8. Li P, Zhao X, Jia CJ, Sun HG, Sun LM, Cheng XF, Liu L, Fan WL, J. Mater. Chem. A, 1(10), 3421 (2013)
  9. Yan J, Shen YH, Li F, Li TH, Sci. World J., 458106 (2013)
  10. Khyzhun OY, Bekenev VL, Atuchin VV, Galashov EN, Shlegel VN, Mater. Chem. Phys., 140(2-3), 588 (2013)
  11. Li HD, Li WJ, Gu SN, Wang FZ, Zhou HL, RSC Adv., 5(109), 89940 (2015)
  12. Keereeta Y, Thongtem S, Thongtem T, Powder Technol., 284, 85 (2015)
  13. Cappella F, Bernabei R, Belli P, Caracciolo V, Cerulli R, Danevich FA, d’Angelo A, Di Marco D, Incicchitti A, Poda DV, Tretyak VI, Eur. Phys. J. C, 73, 2276 (2013)
  14. Belli P, Bernabei R, Cappella F, Cerulli R, Danevich FA, d’Angelo S, Incicchitti A, Kobychev VV, Poda DV, Tretyak VI, J. Phys. G, 38, 115107 (2011)
  15. Amouzegar Z, Naghizadeh R, Rezaie HR, Ghahari M, Aminzare M, Ceram. Int., 41, 1743 (2015)
  16. Lin J, Lin J, Zhu YF, Inorg. Chem., 46(20), 8372 (2007)
  17. Leonard KC, Nam KM, Lee HC, Kang SH, Park HS, Bard AJ, J. Phys. Chem. C, 117, 15901 (2013)
  18. Huang GL, Zhang SC, Xu TG, Zhu YF, Environ. Sci. Technol., 42, 8516 (2008)
  19. Li KB, Xue J, Zhang YH, Wei H, Liu YL, Dong CX, Appl. Surf. Sci., 320, 1 (2014)
  20. Hojamberdiev M, Katsumata K, Morita K, Bilmes SA, Matsushita N, Okada K, Appl. Catal. A: Gen., 457, 12 (2013)
  21. Zhang XL, Li Y, Zhao JL, Wang SG, Li YD, Dai HT, Sun XW, J. Power Sources, 269, 466 (2014)
  22. Wang GL, Hu XL, Wu XM, Li ZJ, Sens. Actuators B-Chem., 205, 61 (2014)
  23. Thibert A, Frame FA, Busby E, Holmes MA, Osterloh FE, Larsen DS, J. Phys. Chem. Lett., 2, 2688 (2011)
  24. Luo M, Liu Y, Hu JC, Liu H, Li JL, ACS Appl. Mater. Interfaces, 4, 1813 (2012)
  25. Eskandari P, Kazemi F, Azizian-Kalandaragh Y, Sep. Purif. Technol., 120, 180 (2013)
  26. Zhang J, He R, Liu XH, Nanotechnology, 24, 505401 (2013)
  27. Bai XJ, Wang L, Zhu YF, ACS Catal., 2, 2769 (2012)
  28. Ruiz-Fuertes J, Lopez-Moreno S, Errandonea D, Lacomba-Perales R, Segura A, Rodrıguez-Hernandez P, Pellicer-Porres J, Munoz A, Romero AH, Gonzalez J, J. Appl. Phys., 107, 083506 (2010)
  29. Chronopoulos D, Karousis N, Zhao S, Wang Q, Shinohara H, Tagmatarchis N, J. Chem. Soc.-Dalton Trans., 43, 7429 (2014)
  30. Su YG, Zhu BL, Guan K, Gao SS, Lv L, Du CF, Peng LM, Hou LC, Wang XJ, J. Phys. Chem. C, 116, 18508 (2012)
  31. Chen SH, Sun SX, Sun HG, Fan WL, Zhao X, Sun X, J. Phys. Chem. C, 114, 7680 (2010)
  32. Ruiz-Fuertes J, Lopez-Moreno S, Lopez-Solano J, Errandonea D, Segura A, Lacomba-Perales R, Munoz A, Radescu S, Rodrıguez-Hernandez P, Gospodinov M, Nagornaya LL, Tu CY, Phys. Rev. B, 86, 125202 (2012)
  33. Xiong SL, Xi BJ, Wang CM, Zou GF, Fei LF, Wang WZ, Qian YT, Chem.-Eur. J., 13, 3076 (2007)
  34. Errandonea D, Manjon FJ, Garro N, Rodrıguez-Hernandez P, Radescu S, Mujica A, Munoz A, Tu CY, Phys. Rev. B, 78, 054116 (2008)
  35. Peng TY, Zhang XH, Zeng P, Li K, Zhang XG, Li XG, J. Catal., 303, 156 (2013)
  36. Sabah A, Siddiqi SA, Ali S, World Acad. Sci. Eng. Technol., 4(9), 532 (2010)
  37. de Oliveira ALM, Ferreira JM, Silva MRS, de Souza SC, Vieira FTG, Longo E, Souza AG, Santos IMG, J. Therm. Anal. Calorim., 97, 167 (2009)
  38. Min YL, Zhang K, Zhao W, Zheng FC, Chen YC, Zhang YG, Chem. Eng. J., 193-194, 203 (2012)
  39. Yang MQ, Xu YJ, J. Phys. Chem. C, 117, 21724 (2013)
  40. Zhang LS, Wang ZT, Wang LZ, Xing Y, Li XF, Zhang Y, Appl. Surf. Sci., 305, 179 (2014)
  41. Ungelenk J, Speldrich M, Dronskowski R, Feldmann C, Solid State Sci., 31, 62 (2014)
  42. Huang GL, Shi R, Zhu YF, J. Mol. Catal. A-Chem., 348(1-2), 100 (2011)
  43. Wang H, Li J, Zhou M, Guan Q, Lu Z, Huo P, Yan Y, J. Ind. Eng. Chem., 30, 64 (2015)
  44. Garadkar KM, Ghule LA, Sapnar KB, Dhole SD, Mater. Res. Bull., 48(3), 1105 (2013)