화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.37, 354-360, May, 2016
DOI10.1016/j.jiec.2016.03.050  Export Citation
Sustainable production of acrolein from biodiesel-derived crude glycerol over H3PW12O40 supported on Cs-modified SBA-15
Rong Liu, Shuting Lyu, and Tiefeng Wang†
  • Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
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The feasibility of producing acrolein from crude glycerol was studied by the dehydration reaction over H3PW12O40 (HPW) supported on Cs-modified SBA-15 (HPW/Cs-SBA). The influence of impurities in crude glycerol was investigated. Only the alkali metal ions caused catalyst deactivation and decreased the acrolein selectivity because they decreased the amount of catalytically effective medium Brønstedacid sites. This problem was solved by glycerol desalination, and a stable acrolein yield of 85% was obtained through 60 h of reaction, which was as good as that with pure glycerol. In addition, HPW/Cs-SBA showed good thermal stability and regeneration ability after the reaction with desalted crude glycerol.
Keywords:Crude glycerol;Dehydration;Acrolein;Alkaline metal ions;Tungstophosphoric acid (HPW)
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