고분자 첨가에 의한 콜타르 핏치의 결정성 및 탄소섬유 물성 변화

김정담; 윤재민; 임연수; 김명수; Jung-Dam Kim; Jae-Min Yun; Yun-Soo Lim; Myung-Soo Kim

Korean Journal of Materials Research, Vol.26, No.4, 173-181, April, 2016

DOI10.3740/MRSK.2016.26.4.173 Export Citation

고분자 첨가에 의한 콜타르 핏치의 결정성 및 탄소섬유 물성 변화

Modification of Coal-Tar-Pitch and Carbon Fiber Properties by Polymer Additives

김정담, 윤재민, 임연수¹, 김명수 ^†

명지대학교 화학공학과
¹명지대학교 신소재공학과

Jung-Dam Kim, Jae-Min Yun, Yun-Soo Lim¹, and Myung-Soo Kim^†

Department of Chemical Engineering, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea
¹Department of Materials Science and Engineering, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea

E-mail:

In order to use coal tar pitch (CTP) as a raw material for carbon fibers, it should have suitable properties such as a narrow range of softening point, suitable viscosity and uniform optical properties. In this study, raw CTP was modified by heat treatment with three types of polymer additives (PS, PET, and PVC) to make a spinnable pitch for carbon fibers. The yield, softening point, C/H ratio, insoluble yield, and meso-phase content of various modified CTPs with polymer additives were analyzed by changing the type of polymer additive and the heat treatment temperature. The purpose of this study was to compare the properties of CTPs modified by polymer addition with those of a commercial CTP. After the pitch spinning, the obtained green fibers were stabilized and carbonized. The properties of the respective fibers were analyzed to compare their uniformity, diameter change, and mechanical properties. Among three polymer additives, PS220 and PET261 pitches were found to be spinnable, but the carbon fibers from PET261 showed mechanical properties comparable with those of a commercial CTP produced by an air-blowing method (OCI284). The CTPs modified with polymer additive had higher β-resin fractions than the CTP with only thermal treatment indicating a beneficial effect of carbon fiber application.

Keywords:coal-tar-pitch;carbon fiber;polystyrene;poly ethylene terephthalate;poly vinyl chloride

[References]

Kim MC, Eom SY, Ryu SK, Edie DD, Korean J. Chem. Eng., 43, 745 (2005)
Oh SM, Park YD, Fuel, 78(15), 1859 (1999)
Ciesinska W, Zielinski J, Bzozowska T, J. Therm. Anal. Calorim., 95, 193 (2009)
Blanco C, Santamaria R, Bermejo J, Menendez R, Carbon, 38, 517 (2000)
Yu BJ, Wang CY, Chen MM, Zheng JM, Qi J, Fuel Process. Technol., 104, 155 (2012)
Fernandez JJ, Figueiras A, Granda M, Bermejo J, Menendez R, Carbon, 33, 295 (1995)
Ko HJ, Park CU, Cho HH, Yoo MJ, Kim MS, Lim YS, Korean J. Mater. Res., 23(5), 276 (2013)
Machnikowski J, Machnikoska H, Brzozowska T, Zielinski J, J. Anal. Appl. Pyrolysis, 65, 147 (2002)
Zielinski J, Pacewska B, Bzozowska T, Machnikowski J, J. Therm. Anal. Calorim., 60, 296 (2000)
Brzozowska T, Zielinski J, Machnikowski J, J. Anal. Appl. Pyrolysis, 48, 45 (1998)
Hwang JS, Lee CH, Cho KH, Kim MS, Kim CJ, Ryu SK, Rhee BS, HWAHAK KONGHAK, 33(5), 551 (1995)
Kim MS, Kim SY, Hwang JC, J. Korean Oil Chemist’s Soc., 14, 77 (1997)
Yoo MJ, Ko HJ, Lim YS, Kim MS, Carbon Lett., 15, 247 (2014)
Panaitescu C, Predeanu G, Int. J. Coal Geol., 71(4), 448 (2007)
Monge JA, Amoros DC, Solano AL, Fuel, 80, 41 (2001)
Cranda M, Casal E, Bermejo J, Menendez R, Carbon, 39, 483 (2001)
Guillen MD, Iglesias MJ, Dominguez A, Blanco CG, Energy Fuels, 6, 518 (1992)
Guillen MD, Iglesias MJ, Dominguez A, Blanco CG, Fuel, 74, 1595 (1995)
Manoj B, Kunjumana AG, Int. J. Electrochem. Sci., 7, 3127 (2012)
Lu C, Xu S, Gan Y, Liu S, Liu C, Carbon, 43, 2295 (2005)
Choi PR, Lee E, Kwon SH, Jung JC, Kim MS, J. Phys. Chem. Solids, 87, 72 (2015)
Aksal C, Mater. Lett., 57, 992 (2002)
Mori T, Yamamura H, Kobayashil H, J. Am. Ceram. Soc., 75, 2420 (1992)
Singh RN, J. Am. Ceram. Soc., 70, 117 (1994)
Singh RN, J. Am. Ceram. Soc., 72, 2339 (1990)
Garrido LB, Aglietti EF, J. European Ceram. Soc., 21, 2259 (2001)
Shi Y, Huang X, Yan D, J. European Ceram. Soc., 24, 393 (1998)
Lee JK, Kim JY, Baeg TL, Lee JS, Sin DW, Ceramics Raw Materials, 13, 234 (2000)

[Related Articles]

[1] Kim MC, Eom SY, Ryu SK, Edie DD, Korean J. Chem. Eng., 43, 745 (2005)

[2] Oh SM, Park YD, Fuel, 78(15), 1859 (1999)

[3] Ciesinska W, Zielinski J, Bzozowska T, J. Therm. Anal. Calorim., 95, 193 (2009)

[4] Blanco C, Santamaria R, Bermejo J, Menendez R, Carbon, 38, 517 (2000)

[5] Yu BJ, Wang CY, Chen MM, Zheng JM, Qi J, Fuel Process. Technol., 104, 155 (2012)

[6] Fernandez JJ, Figueiras A, Granda M, Bermejo J, Menendez R, Carbon, 33, 295 (1995)

[7] Ko HJ, Park CU, Cho HH, Yoo MJ, Kim MS, Lim YS, Korean J. Mater. Res., 23(5), 276 (2013)

[8] Machnikowski J, Machnikoska H, Brzozowska T, Zielinski J, J. Anal. Appl. Pyrolysis, 65, 147 (2002)

[9] Zielinski J, Pacewska B, Bzozowska T, Machnikowski J, J. Therm. Anal. Calorim., 60, 296 (2000)

[10] Brzozowska T, Zielinski J, Machnikowski J, J. Anal. Appl. Pyrolysis, 48, 45 (1998)

[11] Hwang JS, Lee CH, Cho KH, Kim MS, Kim CJ, Ryu SK, Rhee BS, HWAHAK KONGHAK, 33(5), 551 (1995)

[12] Kim MS, Kim SY, Hwang JC, J. Korean Oil Chemist’s Soc., 14, 77 (1997)

[13] Yoo MJ, Ko HJ, Lim YS, Kim MS, Carbon Lett., 15, 247 (2014)

[14] Panaitescu C, Predeanu G, Int. J. Coal Geol., 71(4), 448 (2007)

[15] Monge JA, Amoros DC, Solano AL, Fuel, 80, 41 (2001)

[16] Cranda M, Casal E, Bermejo J, Menendez R, Carbon, 39, 483 (2001)

[17] Guillen MD, Iglesias MJ, Dominguez A, Blanco CG, Energy Fuels, 6, 518 (1992)

[18] Guillen MD, Iglesias MJ, Dominguez A, Blanco CG, Fuel, 74, 1595 (1995)

[19] Manoj B, Kunjumana AG, Int. J. Electrochem. Sci., 7, 3127 (2012)

[20] Lu C, Xu S, Gan Y, Liu S, Liu C, Carbon, 43, 2295 (2005)

[21] Choi PR, Lee E, Kwon SH, Jung JC, Kim MS, J. Phys. Chem. Solids, 87, 72 (2015)

[22] Aksal C, Mater. Lett., 57, 992 (2002)

[23] Mori T, Yamamura H, Kobayashil H, J. Am. Ceram. Soc., 75, 2420 (1992)

[24] Singh RN, J. Am. Ceram. Soc., 70, 117 (1994)

[25] Singh RN, J. Am. Ceram. Soc., 72, 2339 (1990)

[26] Garrido LB, Aglietti EF, J. European Ceram. Soc., 21, 2259 (2001)

[27] Shi Y, Huang X, Yan D, J. European Ceram. Soc., 24, 393 (1998)

[28] Lee JK, Kim JY, Baeg TL, Lee JS, Sin DW, Ceramics Raw Materials, 13, 234 (2000)