화학공학소재연구정보센터
Chemical Engineering Journal, Vol.296, 356-365, 2016
Remediation of pyrene-contaminated soil by active species generated from flat-plate dielectric barrier discharge
In this study, soil polluted with pyrene was remediated using a dielectric barrier discharge (DBD) plasma reactor at atmospheric pressure. Influencing factors, including treatment time, discharge voltage, electrode gap, gas flow rate, initial pyrene concentration, and pH of the soil, were studied. Experimental results showed that pyrene degradation efficiency was influenced on a small scale by soil pH: the pyrene removal rate reached 76% in alkaline condition (pH of 11.69), i.e., 8% higher than in neutral conditions (pH of 7.76) and 13.7% higher than in acidic conditions (pH of 5.67). The removal of pyrene increased as the applied voltage increased and the electrode gap decreased. The optimal airflow rate was 1.0 L/min. The more pyrene that was coated on soil particles the higher was the energy efficiency, but the plasma penetrating pyrene layers faded by approximately 25% when the layers doubled. Optical Emission Spectrometer (OES), FT-IR and GC-MS data indicated that the excited atomic nitrogen, atomic oxygen and NOx were abundant in the plasma, and that the active species containing oxygen and nitrogen both contributed to the decomposition of pollutants. The possible pyrene degradation pathway was suggested. The experimental results showed that the DBD technique was able to effectively degrade pyrene over a broad pH range. (C) 2016 Elsevier B.V. All rights reserved.