Electrochimica Acta, Vol.202, 84-89, 2016
Mass-transport impedance at channel electrodes: accurate and approximate solutions
Accurate numerical electrochemical impedance spectra at channel electrodes are obtained using commercial finite element method software. These agree with experimental measurements on the hexaammineruthenium(II/III) reversible redox couple. The numerical solutions are used as a benchmark to test the validity of some common analytical approximations for the mass -transport impedance. (C) 2016 Elsevier Ltd. All rights reserved.