화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.27, No.3, 227-238, June, 2016
DOI10.14478/ace.2016.1047  Export Citation
금속 나노 촉매를 활용한 선택적 알코올 산화 반응
Supported Metal Nanoparticles: Their Catalytic Applications to Selective Alcohol Oxidation
무하마드 아시프 후세인, 느얀즈 조셉, 강온유, 조용훈, 엄병헌1, 김정원†
  • 강원대학교 에너지공학부
  • 1한국과학기술연구원 천연물연구소
Muhammad Asif Hussain, Nyanzi Joseph, Onyu Kang, Young-Hun Cho, Byung-Hun Um1, and Jung Won Kim†
  • Department of Chemical Engineering, Kangwon National University, Samcheok 25913, Republic of Korea
  • 1Korea Institute of Science and Technology, Republic of Korea
E-mail:
초록
본 리뷰 논문은 지지화된 또는 고정화된 금속들 중 선택적 알코올 산화 반응에 적용된 나노 크기의 여러 금속 촉매들에 대해 집중적으로 서술한다. 금속 나노 촉매들은 넓은 표면적을 지닌 고체 지지체들의 표면 위에 금속 나노 입자들의 고른 분산을 통해 얻어진다. 이러한 나노 촉매들은 유기 합성, 연료 전지, 바이오 디젤 생산, 오일 크래킹, 에너지변환 및 저장, 의약, 수처리, 고체 로켓 추진체, 염료 제조 등 학문적.산업적 측면 모두 다양하게 사용될 수 있다. 더욱이, 응용성이 풍부한 중간체들을 생산하는 호기성 알코올 산화 반응에서 금속 나노 재료는 촉매로써 매우 중요하다. 금, 팔라듐, 류테늄, 바나디움 등과 같은 지지화된 금속 나노 촉매들의 알코올 산화 반응은 기존의 화학 당량적 반응과 달리 비용을 경감시키고 부반응물들을 줄임으로써 경제적이고 친환경적이다. 뿐만 아니라, 상온에서 진행된 나노 촉매 알코올 산화 반응에 대해서도 소개된다.
This review article highlights different types of nano-sized catalysts for the selective alcohol oxidation to form aldehydes (or ketones) with supported or immobilized metal nanoparticles. Metal nanoparticle catalysts are obtained through dispersing metal nanoparticles over a solid support with a large surface area. The nanocatalysts have wide technological applications to industrial and academic fields such as organic synthesis, fuel cells, biodiesel production, oil cracking, energy conversion and storage, medicine, water treatment, solid rocket propellants, chemicals and dyes. One of main reactions for the nanocatalyst is an aerobic oxidation of alcohols to produce important intermediates for various applications. The oxidation of alcohols by supported nanocatalysts including gold, palladium, ruthenium, and vanadium is very economical, green and environmentally benign reaction leading to decrease byproducts and reduce the cost of reagents as opposed to stoichiometric reactions. In addition, the room temperature alcohol oxidation using nanocatalysts is introduced.
Keywords:alcohol oxidation;aldehyde;supported metal;metal nanoparticle;nanocatalyst
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