화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.98, 51-55, 2016
Experimental measurement and correlation of the solubility of aloe-emodin in seven pure solvents
The solubility of aloe-emodin in seven pure solvents namely water, methanol, ethanol, 1-propanol, 1-butanol, 2-butanol, and 1-pentanol was measured by a static analytic method. The measurements were carried out over the temperature range from (278.15 to 318.15) K at 5 K intervals under atmospheric pressure using a UV/vis spectrophotometer analysis. The effects of experimental temperature and solvent type on the solubility are discussed. The relative solubility of aloe-emodin in seven solvents was determined in elevated order to be chi(water) (<) chi(methanol) < chi(ethanol) < chi(2-butanol) < chi(1-propanol) < chi(1-butanol) < chi(1-pentanol). The experimental result shows that 1-pentanol could be a suitable solvent for industrial preparation of aloe-emodin. The experimental solubility values were correlated with the modified Apelblat and lambda h models. It was found that the two empirical thermodynamic models can satisfactorily correlate the solubility of aloe-emodin in the seven solvents over the range of temperature studied. (C) 2016 Elsevier Ltd. All rights reserved.