Mixed valent double perovskite Ba2FeWO6, with tetragonal crystal structure, synthesized in a highly controlled reducing atmosphere, shows antiferromagnetic transition at T-N = 19 K. A cluster glass-like transition is observed around 30 K arising from the competing interactions between inhomogeneous magnetic states. The structural distortion leads to the formation of polarons that are not contributing to DC conduction below charge ordering temperature, T-co = 279 K. Above Tco, small polarons will start to hop by exploiting thermal energy and participate in the conduction mechanism. The polarons are also responsible for the dielectric relaxor behavior, in which the dielectric relaxation time follows non linearity in temperature as proposed by Fulcher. The material also exhibits a small room temperature magnetoresistance of 1.7% at 90 kOe. An intrinsic magnetodielectric coupling of similar to 4% near room temperature and at lower temperatures, as well as an extrinsic magnetodielectric coupling change from +4% to-6% at around 210K are reported. (C) 2015 Elsevier Ltd. All rights reserved.