Ag2CO3/(BiO)(2)CO3 composites have been fabricated in-situ via a facile parallel flaw co-precipitation method. The specific surface area, structure, morphology, and the separation rate of photo-induced charge pairs of the photocatalysts were characterized by Brunauer-Emmett-Teller (BET) method, X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy(DRS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and surface photovoltage (SPV) spectroscopy, respectively. XRD patterns and DRS demonstrated that Ag2CO3 has no effect on the crystal phase and bandgap of (BiO)(2)CO3. The existence of Ag2CO3 in the composites enhances the separation rate of photo-induced charge pairs of the photocatalysts. The photocatalytic performance of Ag2CO3/(BiO)(2)CO3 was evaluated by the decolorization of methyl orange (MO) aqueous solution under simulated solar irradiation. It was found that the simulated solar-induced photocatalytic activity of Ag2CO3/(BiO)(2)CO3 copmposites was significantly improved, which was mainly attributed to the enhanced surface area and the separation rate of photo-induced charge pairs. (C) 2016 Elsevier Ltd. All rights reserved.