Swelling/deswelling self-oscillating of microgels induced by the BZ reaction with Fe(phen)3 catalyst

Jie Ren; Jinfen Gu; Li Tao; Guangcheng Zhang; Wu Yang

Macromolecular Research, Vol.24, No.6, 502-507, June, 2016

DOI10.1007/s13233-016-4076-7 Export Citation

Swelling/deswelling self-oscillating of microgels induced by the BZ reaction with Fe(phen)3 catalyst

Jie Ren^†, Jinfen Gu, Li Tao, Guangcheng Zhang¹, and Wu Yang

Chemistry & Chemical Engineering College, Northwest Normal University, Key Lab of Bioelectrochemtry & Environmental Analysis of Gansu, Lanzhou, 730070, P. R. China
¹School of Natural and Applied Science, Northwestern Polytechnical University, Xi’an, 710072, P. R. China

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A novel kind of microgels, poly(NIPAAm-co-Fe(phen)3-co-AAc), were prepared by copolymerization N-isopropylacrylamide (NIPAAm), acrylic acid (AAc) and iron(II) 5-acrylamide-1,10-phenanthroline-bi(1,10-phenanthroline) (Fe(phen)3), the catalyst for the Belousov-Zhabotinsky (BZ) reaction. The microgels were characterized by FT-IR spectroscopy, X-ray photoelectron spectroscopy (XPS), dynamic light scattering (DLS) and scanning electron microscope (SEM). In addition, the self-oscillating behaviors of the microgels were investigated in BZ system free of catalyst. Both the redox potential and transmittance self-oscillation were observed. Moreover, the amplitudes of poly(NIPAAm-co-Fe(phen)3-co-AAc) microgels are much larger than those of linear polymer and gel. This advantage originated from the special structure, size and composition of the microgels.

Keywords:swelling/deswelling self-oscillation;microgels;BZ oscillating chemical reaction

[References]

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Ren J, Yao MQ, Zhang GC, Yang XC, Gu JF, Yang W, J. Polym. Res., 22, 44 (2015)
Ren J, Yao MQ, Zhang GC, Yang XC, Gu JF, Yang W, J. Polym. Res., 22, 197 (2015)

[Referenced By]

[1] Kawaguchi H, Prog. Polym. Sci, 25, 1171 (2000)

[2] Tanaka T, Fillmore DJ, J. Chem. Phys., 70, 1214 (1979)

[3] Kawaguchi H, Polym. Int., 63, 925 (2014)

[4] Wu W, Shen J, Li Y, Biomaterials, 33, 7115 (2012)

[5] Farooqi ZH, Khan HU, Shah SM, Arab. J. Chem., 10.1016/j.arabjc.2013.07.031 (2013)

[6] Brigger I, Dubernet C, Couvreur P, Adv. Drug Deliv. Rev., 54, 631 (2002)

[7] Zhang JG, Xu SQ, Kumacheva E, J. Am. Chem. Soc., 126(25), 7908 (2004)

[8] Lee J, Park JC, Song H, Adv. Mater., 20(8), 1523 (2008)

[9] Retama JR, Lopez-Ruiz B, Lopez-Cabarcos E, Biomaterials, 24, 2965 (2003)

[10] Pelton R, Adv. Colloid Interface Sci., 85, 1 (2000)

[11] Khan A, J. Colloid Interface Sci., 313(2), 697 (2007)

[12] Jones CD, Lyon LA, Langmuir, 19(11), 4544 (2003)

[13] Kim J, Serpe MJ, Lyon LA, J. Am. Chem. Soc., 126(31), 9512 (2004)

[14] Debord SB, Lyon LA, J. Phys. Chem. B, 107(13), 2927 (2003)

[15] Yoshida R, Takahashi T, Yamaguchi T, Ichijo H, J. Am. Chem. Soc., 118(21), 5134 (1996)

[16] Shiota T, Ikura YS, Nakata S, J. Phys. Chem. B, 117(7), 2215 (2013)

[17] Nakamaru S, Maeda S, Hara Y, Hashimoto S, J. Phys. Chem. B, 113(14), 4609 (2009)

[18] Suzuki D, Taniguchi H, Yoshida R, J. Am. Chem. Soc., 131(34), 12058 (2009)

[19] Suzuki D, Kobayashi T, Yoshida R, Hirai T, Soft Matter., 8, 1447 (2012)

[20] Suzuki D, Yoshida R, J. Phys. Chem. B, 112(40), 12618 (2008)

[21] Taniguchi H, Suzuki D, Yoshida R, J. Phys. Chem. B, 114(7), 2405 (2010)

[22] Arimura T, Mukai M, Chem. Commun., 50, 5861 (2014)

[23] Ren J, Yao MQ, Zhang GC, Yang XC, Gu JF, Yang W, J. Polym. Res., 22, 44 (2015)

[24] Ren J, Yao MQ, Zhang GC, Yang XC, Gu JF, Yang W, J. Polym. Res., 22, 197 (2015)