화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.39, 16-20, July, 2016
Dyeing of electrospun nylon 6 nanofibers with reactive dyes using electron beam irradiation
E-mail:,
Nylon 6 nanofibers were prepared by using an electrospinning technique. The dyeing behavior of nylon 6 nanofibers which were dyed with reactive dyes, vinylsulphone type-Remazol Red RR, by electron beam irradiation (EBI) has been investigated. Electrospun nylon 6 nanofibers were irradiated varying EBI doses of 10, 20, 30, 40, 50, 100 kGy and their K/S values, Lab values and dyeing equilibrium were observed. No additives and toxic reagents were used for dyeing nylon 6 nanofibers with reactive dyes using radiation. Compared with conventional dyeing method, it is found that irradiated dyeing of nylon 6 nanofibers with reactive dyes has improved not only the color strength and fiber-shrink phenomenon but also the scission reactions of functional groups of Remazol Red RR at EBI dose greater than 10 kGy. This finding suggests that the dyeing by EBI significantly influence the waste-water treatment in a green way. The resulting dyed nylon 6 nanofibers were characterized using scanning electron microscopy (SEM) and UV-Visible spectroscopy.
  1. Marcucci M, Ciardelli G, Matteucci A, Ranieri L, Russo M, Desalination, 149(1-3), 137 (2002)
  2. Khatri Z, Mayakrishnan G, Hirata Y, Wei K, Kim IS, Carbohydr. Polym., 91, 434 (2013)
  3. Khatri Z, Memon HM, Khatri A, Tanwari A, Ultrason. Sonochem., 18, 1301 (2011)
  4. Ma W, Zhang SF, Tang BT, Yang JZ, Color. Technol., 12, 1193 (2005)
  5. Soleimani-Gorgani A, Taylor JA, Dyes Pigment., 68, 109 (2006)
  6. Soleimani-Gorgani A, Taylor JA, Dyes Pigment., 76, 610 (2008)
  7. Burkinshaw SM, Wills AE, Dyes Pigment., 34, 243 (1997)
  8. Akyol A, Yatmaz HC, Bayramoglu M, Appl. Catal. B: Environ., 54(1), 19 (2004)
  9. Allegre C, Moulin P, Maisseu M, Charbit F, Desalination, 162(1-3), 13 (2004)
  10. Correia VM, Stephenson T, Judd SJ, Environ. Technol., 15, 917 (1994)
  11. Yoon B, Lee S, Fib. Polym., 12, 57 (2011)
  12. Ma ZW, Kotaki M, Ramakrishna S, J. Membr. Sci., 265(1-2), 115 (2005)
  13. Kim BS, Kimura N, Kim HK, Watanabe K, Kim IS, J. Nanosci. Nanotechnol., 11, 4929 (2011)
  14. Lee S, Kimura D, Yokoyama A, Lee KH, Park JC, Kim IS, Textile Res. J., 79, 1085 (2009)
  15. Lee S, Kimura D, Lee KH, Park JC, Kim IS, Textile Res. J., 80, 99 (2010)
  16. Pant HR, Baek WI, Nam KT, Jeong IS, Barakat NAM, Kim HY, Polymer, 52(21), 4851 (2011)
  17. Pey JL, Anti-Cor. Meth. Mater., 44, 94 (1997)
  18. Pant HR, Bajgai MP, Nam KT, Seo YA, Pandeya DR, Hong ST, Kim HY, J. Hazard. Mater., 185, 124 (2011)
  19. Kim H, Bae JS, Fib. Polym., 10, 320 (2009)
  20. Hakeim OA, Abdou LAW, El-Gammal MS, El-Naggar AM, Carbohydr. Polym., 87(1), 467 (2012)
  21. Park M, Pant B, Choi J, Park YW, Lee C, Shin HK, Park SJ, Kim HY, Carbon Lett., 15(1), 36 (2014)
  22. Ji BC, Rabbani MM, Bae SS, Shin JC, Yang SB, Choi WS, Park YS, Do KB, Yeum JH, Polym. Polym. Compos., 22, 519 (2014)
  23. Wang X, Fan L, Gong D, Zhu J, Zhang Q, Lu B, Adv. Funct. Mater., 26, 1143 (2016)
  24. Zhu J, Chen L, Xu Z, Lu B, Nano Energy, 12, 339 (2015)
  25. Nam KT, Pant HR, Jeong JW, Pant B, Kim BI, Kim HY, Polym. Degrad. Stabil., 96, 1984 (2011)
  26. Park M, Kim BS, Shin HK, Park SJ, Kim HY, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 33, 5051 (2013)
  27. Park M, Shin HK, Kim BS, Pant B, Nasser AMB, Kim HY, Mater. Lett., 105, 236 (2013)