Facile construction of electrically-conductive carbon patterns from a cheap coal-type pitch and their application to electric heating devices

Jin-Mook Jung; Ji-Hyun Hong; In-Tae Hwang; Junhwa Shin; Young-Ju Kim; Young Gyu Jeong; Chan-Hee Jung; Jae-Hak Choi

Journal of Industrial and Engineering Chemistry, Vol.39, 188-193, July, 2016

DOI10.1016/j.jiec.2016.05.023 Export Citation

Facile construction of electrically-conductive carbon patterns from a cheap coal-type pitch and their application to electric heating devices

Jin-Mook Jung^{1, 2}, Ji-Hyun Hong^{1, 2}, In-Tae Hwang^{1, 3}, Junhwa Shin^{1, 3}, Young-Ju Kim⁴, Young Gyu Jeong^{4, †}, Chan-Hee Jung^{1, 3, †}, and Jae-Hak Choi^{2, †}

¹Research Division for Industry and Environment, Korea Atomic Energy Research Institute, Jeollabuk-do 580-185, South Korea
²Department of Polymer Science and Engineering, Chungnam National University, Daejeon 305-764, South Korea
³, Korea
⁴Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon 305-764, South Korea

E-mail:, ,

Electrically-conductive carbon patterns (ECPs) from cheap pitch thin films were fabricated using a simple proton beam lithography and pyrolysis. Well-defined negative-type pitch patterns were formed at the optimized fluence of 3 × 1015 ions cm-2, and then pyrolyzed at various temperatures to create ECPs. The precursory pitch patterns formed at the optimized conditions were successfully temperature-dependently converted to the ECPs by pyrolysis. The formed ECPs through pyrolysis at a higher temperature exhibited good electrical conductivity. Moreover, the ECPs exhibited good electric heating characteristics, demonstrating the possibility of using the ECPs as a cheap electric heating element.

Keywords:Conductive carbon patterns;Pitch;Proton beam lithography;Pyrolysis;Electric heating

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[2] Zhang J, Zhao Y, Wei ZM, Sun YM, He YD, Di CA, Xu W, Hu WP, Liu YQ, Zhu DB, Adv. Funct. Mater., 21(4), 786 (2011)

[3] Mysyk R, Pinero ER, Beguin F, Electrochem. Commun., 11, 554 (2009)

[4] Hakan M, Braake YJT, Aran HC, Stamatialis DF, Wessling M, J. Membr. Sci., 349(1-2), 231 (2010)

[5] Sharma P, Damien D, Nagarajan K, Shaijumon MM, Hariharan M, J. Phys. Chem. Lett., 4, 3192 (2013)

[6] Xi S, Shi T, Long H, Xu L, Tang Z, Microsyst. Technol., 21, 1835 (2015)

[7] Lee K, Park J, Lee MS, Kim J, Hyun BG, Kang DJ, Na K, Lee CY, Bien F, Park JU, Nano Lett., 14, 2647 (2014)

[8] Jung CH, Kim WJ, Jung CH, Hwang IT, Khim D, Kim DY, Lee JS, Ku BC, Choi JH, Carbon, 87, 257 (2015)

[9] Wang X, Zhi L, Tsao N, Tomovic Z, Li J, Mullen K, Angew. Chem.-Int. Edit., 47, 2990 (2008)

[10] Hu LB, Hecht DS, Gruner G, Chem. Rev., 110(10), 5790 (2010)

[11] Ren S, Li R, Meng X, Li H, J. Mater. Chem., 22, 6171 (2012)

[12] Du J, Pei S, Ma L, Cheng HM, Adv. Mater., 18, 1958 (2014)

[13] Seguchi T, Kudoh H, Sugimoto M, Hama Y, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 151, 154 (1999)

[14] Li Y, Lee EJ, Cai W, Kim KY, Cho SO, ACS Nano, 2, 1108 (2008)

[15] Chennamsetty R, Escobar I, Xu XL, Desalination, 188(1-3), 203 (2006)

[16] Hwang IT, Oh MS, Jung CH, Choi JH, Biotechnol. Lett., 36(10), 2135 (2014)

[17] Sarkar M, Shukla N, Banerji N, Mohapatra YN, Appl. Surf. Sci., 258(9), 4195 (2012)

[18] Brun S, Savu V, Schintke S, Guibert E, Keppner H, Brugger J, Whitlow HJ, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 306, 292 (2013)

[19] Morilla IG, Abraham MH, de Kerckhove DG, Grime GW, J. Micromech. Microeng., 15, 706 (2005)

[20] Mendez A, Santamaria R, Menendez R, Bermejo J, J. Anal. Appl. Pyrolysis, 58-59, 825 (2001)

[21] Lee JS, Joh HI, Kim TW, Lee S, Org. Electron., 15, 132 (2014)

[22] Tejero VC, Carrasco S, Villoslada FN, Fierro JLG, Sanchez MDCC, Bondi MCM, Barrios CA, J. Mater. Chem. C, 1, 1392 (2013)

[23] Jones SP, Fain CC, Edie DD, Carbon, 35, 1533 (1997)

[24] Akrami HA, Yardim MF, Akar A, Ekinci E, Fuel, 76(14), 1389 (1997)

[25] Cristadoro A, Kulkarni SU, Burgess WA, Cervo EG, Rader HJ, Mullen K, Bruce DA, Thies MC, Carbon, 47, 2358 (2009)

[26] Tzeng SS, Pan JH, Mater. Chem. Phys., 74(2), 214 (2002)

[27] Petrova B, Budinova T, Petrov N, Yardim MF, Ekinci E, Razvigorova M, Carbon, 43, 261 (2005)

[28] Diez N, Alvarez P, Granda M, Blanco C, Santamaria R, Menendez R, Chem. Eng. J., 260, 463 (2015)

[29] Yoon SB, Chai GS, Kang SK, Yu JS, Gierszal KP, Jaroniec M, J. Am. Chem. Soc., 127(12), 4188 (2005)

[30] Ishihara A, Kawashima K, Wang XS, Shono H, Kabe T, Energy Fuels, 10(3), 726 (1996)

[31] Jain IP, Agarwal G, Surf. Sci. Rep., 66, 77 (2011)

[32] Du R, Ssenyange S, Aktary M, McDermott MT, Small, 5, 1162 (2009)

[33] Zhang YL, Guo L, Wei S, He YY, Xia H, Chen QD, Sun HB, Xiao FS, Nano Today, 5(1), 15 (2010)

[34] Wang Y, Serrano S, Santiago-Aviles JJ, J. Mater. Sci. Lett., 21(13), 1055 (2002)