화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Materials Research, Vol.26, No.6, 311-319, June, 2016
DOI10.3740/MRSK.2016.26.6.311  Export Citation
폐과일껍질을 이용한 친환경 ZnO 나노분말 합성
Enviroment-Friendly Synthesis of Nanocrystalline Zinc Oxide Particles Using Fruit Peel Extract
R. Yuvakkumar, 송재숙, 신평우1, 홍순익†
  • 충남대학교 신소재공학과
  • 1창원대학교 금속신소재공학과
R. Yuvakkumar, Jae Sook Song, Pyung Woo Shin1, and Sun Ig Hong†
  • Department of Nanomaterials Engineering, Chungnam National University, Daejeon 34134, Republic of Korea
  • 1Department of Metallurgy & Advanced Materials Engineering, Changwon National University, Changwon 61140, Republic of Korea
E-mail:
In this study, an environment-friendly synthetic strategy to process zinc oxide nanocrystals is reported. The biosynthesis method used in this study is simple and cost-effective, with reduced solvent waste via the use of fruit peel extract as a natural ligation agent. The formation of ZnO nanocrystals using a rambutan peel extract was observed in this study. Rambutan peels has the ability to ligate zinc ions as a natural ligation agent, resulting in ZnO nanochain formation due to the presence of an extended polyphenolic system over the whole incubation period. Via transmission electron microscopy, successful formation of zinc oxide nanochains was confirmed. TEM observation revealed that the bioinspired ZnO nanocrystals were spherical and/or hexagonal particles with sizes between 50 and 100 nm.
Keywords:green synthesis;zinc oxide;fruit peel waste;nanocrystal
  1. Iravani S, Green Chem., 13, 2638 (2011)
  2. Patete JM, Peng X, Koenigsmann C, Xu Y, Karnb B, Wong SS, Green Chem., 13, 482 (2011)
  3. Wenda S, Illner S, Mell A, Kragl U, Green Chem., 13, 3007 (2011)
  4. Konishi Y, Ohno K, Saitoh N, Nomura T, Nagamine S, Hishida H, Takahashi Y, Uruga T, J. Biotechnol, 128, 648 (2007)
  5. Das SK, Dickinson C, Lafir F, Brougham DF, Marsili E, Green Chem., 14, 1322 (2012)
  6. Chandran SP, Chaudhary M, Pasricha R, Ahmad A, Sastry M, Biotechnol. Prog., 22(2), 577 (2006)
  7. Philip D, Physica E, 42, 1417 (2010)
  8. Chu SY, Yan TM, Chen SL, J. Mater. Sci. Lett., 19(4), 349 (2000)
  9. Tokumoto MS, Briois V, Santilli CV, J. Sol-Gel Sci. Technol., 26, 547 (2003)
  10. Kim JH, Choi WC, Kim HY, Kang Y, Park YK, Powder Technol., 153(3), 166 (2005)
  11. Damonte LC, Zelis LAM, Soucase BM, Fenollosa MAH, Powder Technol., 148(1), 15 (2004)
  12. Kahn ML, Monge M, Adv. Funct. Mater., 3, 458 (2005)
  13. Komarneni S, Bruno M, Mariani E, Mater. Res. Bull., 35(11), 1843 (2000)
  14. Zhao XY, Zheng BC, Li CZ, Gu HC, Powder Technol., 100(1), 20 (1998)
  15. Tani T, Madler L, Pratsinis SE, J. Nanopart. Res., 4, 337 (2002)
  16. Dai ZR, Pan ZW, Wang ZL, Adv. Funct. Mater., 13(1), 9 (2003)
  17. Ao WQ, Li JQ, Yang HM, Zeng XR, Ma XC, Powder Technol., 168(3), 148 (2006)
  18. Yu D, Cai R, Liu Z, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 60, 1617 (2004)
  19. Curri ML, Comparelli R, Cozzli PD, Mascolo G, Agostiano A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 23, 285 (2003)
  20. Kamat PV, Huehn R, Nicolaescu R, J. Phys. Chem. B, 106(4), 788 (2002)
  21. Lin HM, Tzeng SJ, Hsiau PJ, Tsai WL, Nanostruct. Mater., 10, 465 (1998)
  22. Xu J, Pan QY, Shun YA, Tian ZZ, Sens. Actuators B-Chem., 66, 277 (2000)
  23. Hu ZS, Oskam G, Searson PC, J. Colloid Interface Sci., 263(2), 454 (2003)
  24. Chen SJ, Li LH, Chen XT, Xue ZL, Hong JM, You XZ, J. Cryst. Growth, 252(1-3), 184 (2003)
  25. Li AK, Wu WT, Key Eng. Mater., 247, 405 (2003)
  26. Song JY, Kim BS, Bioprocess. Biosyst. Eng., 32, 79 (2009)
  27. Gorinstein S, Zemser M, Haruenkit R, Chuthakorn R, Grauer F, Belloso OM, Trakhtenberg S, J. Nutr. Biochem., 10, 367 (1999)
  28. Leong LP, Shui G, Food Chem., 76, 69 (2002)
  29. Palanisamy U, Cheng HM, Masilamani T, Subramaniam T, Ling LT, Radhakrishnan AK, Food Chem., 109, 54 (2008)
  30. Thitilertdecha N, Teerawutgulrag A, Rakariyatham N, LWT - Food Sci. Technol., 41, 2029 (2008)
  31. Daman TC, Proto SPS, Tell B, Phys. Rev., 142, 570 (1966)
  32. Hong RY, Li JH, Chen LL, Liu DQ, Li HZ, Zheng Y, Ding J, Powder Technol., 189(3), 426 (2009)
  33. Wang XB, Huo KF, Zhang F, Hu Z, Chu PK, Tao HS, Wu Q, Hu YM, Zhu JM, J. Phys. Chem. C, 113, 170 (2009)
  34. Jayaseelan C, Rahuman AA, Kirthi AV, Marimuthu S, Santhoshkumar T, Bagavan A, Gaurav K, Karthik L, Rao KVB, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 90, 78 (2012)
  35. Barnaby SN, Yu SM, Fath KR, Tsiola A, Khalpari O, Banerjee IA, Nanotechnology, 22, 225605 (2011)
  36. Koren E, Kohen R, Ginsburg IA, J. Agric. Food Chem., 57, 7644 (2009)
  37. Jacob JA, Mahal HS, Biswas N, Mukherjee T, Kapoor S, Langmuir, 24(2), 528 (2008)
  38. McDonald M, Mila I, Scalbert A, J. Agric. Food Chem., 44, 599 (1996)
  39. Sivaraman SK, Elango I, Kumar S, Santhanam V, Curr. Sci., 97, 1055 (2009)
  40. Yamamoto O, Sawai J, Sasamoto T, Int. J. Inorg. Mater., 2, 451 (2000)
  41. Przewloka SR, Shearer BJ, Holzforschuang, 56, 13 (2002)