A type of Pd/alpha-Fe2O3 catalyst was synthesized by a convenient UV light-induced reduction in the presence of Fe3+ ions. The synthesized Pd/alpha-Fe2O3 particles were characterized by X-ray diffraction (XRD), low-resolution transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectrum (XPS), atomic force microscope (AFM), scan electron microscopy with energy dispersion spectra (SEM-EDS), FT-IR and BET. Related characterizations confirm that IN light-induced reduction is a feasible, simply and environment-friendly method for the preparation of supported catalysts containing active metal. Furthermore, hydrogenation of o-chloronitrobenzene (o-CNB) to o-chloroaniline (o-CAN) by the selected Pd(0.5%)/alpha-Fe2O3 was investigated systematically. The alpha-Fe2O3-supported Pd catalyst was found to exhibit good catalytic activity and selectivity for the o-CNB reduction under mild conditions. The hydrogenation of o-CNB over the resulting Pd-based catalyst gave a 100% o-CNB conversion and 91.4% selectivity of o-CAN under the reaction conditions of 50 degrees C, 2 h, 1 MPa hydrogen pressure, n(0-CNB)/n(Pd) = 6000:1. Moreover, the resulting Pd-based catalyst remained higher hydrogenation reactivity after three runs even if a sharply decrease in activity was observed at the fourth run. The obtained results reveal the as-prepared Pd/alpha-Fe2O3 is an efficient catalyst for the hydrogenation of o-CNB even at a high level of substrate concentration. (C) 2016 Elsevier B.V. All rights reserved.