The study proposes a base kinetic model of biodiesel fuels to distinguish mass-spectrometrically measured hydrocarbons, carbonyl compounds and light-weight polycyclic aromatic hydrocarbons (PAHs) in a methane/air non-premixed flame doped with methyl butanoate (MB). The computational procedure starts with reducing a detailed MB mechanism to generate a minimized but reasonably accurate skeletal mechanism which is then used to combine with previously published submodels that describe PAHs and related compounds. The newly derived MB-PAH mechanism with 83 species and 520 reactions is systematically validated against results of existing detailed and skeletal MB mechanisms. Without empirical adjustment of rate constants in elementary reactions, the MB-PAH mechanism incorporated into a 2-D axisymmetric laminar finite-rate model, for the first time, is able to predict experimentally measured centerline mole fractions of 14 intermediates. The computationally identified intermediates are in accordance with the mass-spectrometric determinations, where the species include propyne/propadiene (C3H4), propene (C3H6), vinylacetylene (C4H4), but-1-ene/but-2-ene (C4H8), ketenes (CH3CHCO and C2H3CHCO), prop-2-enal (C2H3CHO), 1,3,5-Hexatriyne (C6H2), benzene (C6H6), naphthalene (C10H8), phenanthrene (C14H10) and pyrene (C16H10). Moreover, the reaction pathway analysis reveals the correlation between the decomposition of MB and formation of the investigated intermediates. (C) 2016 Elsevier Ltd. All rights reserved.