A Ferromagnetic Salicylaldoximate/Azide (Mn2Mn6III)-Mn-II Cluster with an S=17 Ground State and a Single-Molecule-Magnet Response

Vicente R; El Fallah MS; Casanovas B; Font-Bardia M; Escuer A

Inorganic Chemistry, Vol.55, No.12, 5735-5737, 2016

DOI10.1021/acs.inorgchem.6b00662 Export Citation

A Ferromagnetic Salicylaldoximate/Azide (Mn2Mn6III)-Mn-II Cluster with an S=17 Ground State and a Single-Molecule-Magnet Response

Vicente R, El Fallah MS, Casanovas B, Font-Bardia M, Escuer A

One new (Mn2Mn6III)-Mn-II duster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking Mn-3(III)-salicylaldoximate triangles and tetracoordinated Mn-II cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.