Journal of Colloid and Interface Science, Vol.477, 34-39, 2016
Down shifting in poly(vinyl alcohol) gels doped with terbium complex
Novel poly(vinyl alcohol) (PVA) based soft gels with luminescent properties are detailed in this contribution. Lanthanide complex of terbium ions with anthranilic acid, Tb(ant)(3 center dot)2H(2)O, was synthesized and incorporated into a DMSO/water solution, followed by addition of PVA, to attain soft gels at room temperature. Morphological and thermal analyses revealed homogeneous distribution of Tb(ant)(3)center dot 2H(2)O into the PVOH/DMSO/water gel, and that incorporation of the terbium complex does not alter the thermal properties of the gels. The gels are transparent and luminescent, as they exhibit Large Stokes shift down shifting (LSS DS) up to 400 nm, with very high emission quantum yield, that was found to be function of Tb complex concentration. (C) 2016 Elsevier Inc. All rights reserved.