이중 측쇄 폴리이타코네이트 가소화 겔 이온전도성 고분자의 제조 및 전기적 성질

이희우; 박정기; 공명선

Polymer(Korea), Vol.22, No.6, 872-879, November, 1998

Export Citation

이중 측쇄 폴리이타코네이트 가소화 겔 이온전도성 고분자의 제조 및 전기적 성질

Preparation and Electrical Properties of Double-Comblike Polyitaconate Plasticized Gel Ion-Coducting Polymers

이희우, 박정기, 공명선

초록

새로운 종류의 이중 측쇄 이온배위능을 가지는 고분자 고체 전해질을 제조하기 위해서 bis(MEE)itaconate 단량체를 2-(2-methoxyethoxy)ethanol과 itaconic acid를 에스테르화 반응하여 합성하였다. 이온전도성 고분자 필름은 bis(MEE)itaconate, diethylene glycol dimethacrylate 그리고 LiClO₄의 혼

For a new double comblike ion conducting solid polymer electrolyte, bis[2-(2-methoxyethoxy)ethyl]itaconate (bis(MEE)itaconate) monomer was prepared from itaconic acid and 2-(2-methoxyethoxy)ethanol. The ion conducting polymer films were prepared by photoinitiated radical polymerization of bis(MEE)itaconate, diethyleneglycol dimethacrylate and LiClO₄ with benzoin methyl ether(BME) as a photoinitiator. The plasticized polymer gel electrolytes were also prepared by photopolymerization in the presence of ethylene carbonate/propylene carbonate. EC/PC (1/1, 70 ~ 150 mol%) as a plasticizer, 5 ~ 10 % of crosslinker and concentration of alkali salt [EO]/[Li⁺]=10/1, 8/1 and 6/1 were used The optimum [EO]/[Li⁺] ratio for high ion conductivity was found to be 8. The crosslinked polymer gel alkali salt complexes showed ion conductivity 5.6 x 10^-6 S/cm and the EC/PC plasticized polymer gel electrolytes showed ionic conductivity 3.6 x 10^-4 S/cm. They showed a rubber elasticity and maintained a mechanical stability as a free standing film.

Keywords:ion conducting;polymer;polyitaconate;gel electrolyte;ethylene carbonate propylene carbonate;double comblike polymer

[References]

MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I & II," Elsevier Applied Science, New York (1987)
Skotheim TA, "Electroresponsive Molecular and Polymeric System," vol. 1, p. 41-95, Marcel Dekker Inc., New York & Basel (1988)
Linford RG, "Electrochemical Science and Technology of Polymers-I," p. 45-66, Elsevier Applied Science, London & New York (1987)
Baugham RH, Bredas JL, Cgance RR, Eckhardt H, Elsenbaumer RL, Ivory DM, Miller GC, Preiziosi AF, Schacklette LW, "Conductive Polymers," p. 137, Plenum Publ. Corp., New York (1981)
Fenton DE, Parker JE, Wright PV, Polymer, 14, 589 (1973)
Wright PV, Br. Polym. J., 7, 319 (1975)
Fauteux D, Robitaille C, J. Electrochem. Soc., 133, 315 (1986)
Kobayashi N, Hamada T, Ohno H, Tsuchida E, Polym. J., 18, 661 (1986)
Cowie JMG, Martin ACS, Firth AM, Br. Polym. J., 20, 247 (1988)
Blonsky PM, Shriver DF, Austin PE, Allcock HR, J. Am. Chem. Soc., 106, 6854 (1984)
Inoue K, Nishikawa Y, Tanigaki T, J. Am. Chem. Soc., 113, 7609 (1991)
Cowie JMG, Martin ACS, Firth AM, Polymer, 28, 627 (1987)
Fish D, Kahn IM, Wu E, Smid J, Br. Polym. J., 20, 281 (1988)
Allcock HR, Austin PE, Neenan TX, Sisko JT, Blonsky PM, Shriver DF, Macromolecules, 19, 1508 (1986)
Tada H, Fusino K, Kawahara H, J. Polym. Sci. A: Polym. Chem., 25, 3015 (1987)
Watanabe M, Sansui K, Ogata N, Inoue F, Kobayashi T, Ohtaki Z, Polym. J., 17, 549 (1985)
Kim H, Kim E, Rhee SB, Korea Polym. J., 4(2), 83 (1996)
Moon SI, Gong MS, Polym.(Korea), to submitted
Coltrain BK, Ferrar WT, Salva JM, J. Polym. Sci. A: Polym. Chem., 31, 2261 (1993)
Nakamura H, Seno M, Sato T, J. Polym. Sci. A: Polym. Chem., 35(1), 153 (1997)
Kim HC, Gu HB, J. Korean Electrical Electronic Mater. Eng., 7(6), 543 (1994)
Kim JU, Moon SI, Jin BS, Gu HB, Yun MS, J. Korean Electrical Electronic Mater. Eng., 8(4), 487 (1995)

[Referenced By]

[1] MacCallum JR, Vincent CA, "Polymer Electrolyte Reviews I & II," Elsevier Applied Science, New York (1987)

[2] Skotheim TA, "Electroresponsive Molecular and Polymeric System," vol. 1, p. 41-95, Marcel Dekker Inc., New York & Basel (1988)

[3] Linford RG, "Electrochemical Science and Technology of Polymers-I," p. 45-66, Elsevier Applied Science, London & New York (1987)

[4] Baugham RH, Bredas JL, Cgance RR, Eckhardt H, Elsenbaumer RL, Ivory DM, Miller GC, Preiziosi AF, Schacklette LW, "Conductive Polymers," p. 137, Plenum Publ. Corp., New York (1981)

[5] Fenton DE, Parker JE, Wright PV, Polymer, 14, 589 (1973)

[6] Wright PV, Br. Polym. J., 7, 319 (1975)

[7] Fauteux D, Robitaille C, J. Electrochem. Soc., 133, 315 (1986)

[8] Kobayashi N, Hamada T, Ohno H, Tsuchida E, Polym. J., 18, 661 (1986)

[9] Cowie JMG, Martin ACS, Firth AM, Br. Polym. J., 20, 247 (1988)

[10] Blonsky PM, Shriver DF, Austin PE, Allcock HR, J. Am. Chem. Soc., 106, 6854 (1984)

[11] Inoue K, Nishikawa Y, Tanigaki T, J. Am. Chem. Soc., 113, 7609 (1991)

[12] Cowie JMG, Martin ACS, Firth AM, Polymer, 28, 627 (1987)

[13] Fish D, Kahn IM, Wu E, Smid J, Br. Polym. J., 20, 281 (1988)

[14] Allcock HR, Austin PE, Neenan TX, Sisko JT, Blonsky PM, Shriver DF, Macromolecules, 19, 1508 (1986)

[15] Tada H, Fusino K, Kawahara H, J. Polym. Sci. A: Polym. Chem., 25, 3015 (1987)

[16] Watanabe M, Sansui K, Ogata N, Inoue F, Kobayashi T, Ohtaki Z, Polym. J., 17, 549 (1985)

[17] Kim H, Kim E, Rhee SB, Korea Polym. J., 4(2), 83 (1996)

[18] Moon SI, Gong MS, Polym.(Korea), to submitted

[19] Coltrain BK, Ferrar WT, Salva JM, J. Polym. Sci. A: Polym. Chem., 31, 2261 (1993)

[20] Nakamura H, Seno M, Sato T, J. Polym. Sci. A: Polym. Chem., 35(1), 153 (1997)

[21] Kim HC, Gu HB, J. Korean Electrical Electronic Mater. Eng., 7(6), 543 (1994)

[22] Kim JU, Moon SI, Jin BS, Gu HB, Yun MS, J. Korean Electrical Electronic Mater. Eng., 8(4), 487 (1995)