화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.40, 40-46, August, 2016
DOI10.1016/j.jiec.2016.06.001  Export Citation
cis-Cyclooctene epoxidation catalyzed by bulk metallophthalocyanines, metallohexadecafluorophthalocyanines and hollow silica-supported metallohexadecafluorophthalocyanine
Khanh B. Vu†, and Thanh Khoa Phung
  • NTT Hi-Tech Institute, Nguyen Tat Thanh University, 298-300A Nguyen Tat Thanh Street, Ho Chi Minh City, Viet Nam, Vietnam
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We employed a variety of catalysts including metallophthalocyanines and metallohexadecafluor- ophthalocyanines for epoxidation of cis-cyclooctene in water as a green solvent. Manganese phthalocyanine and poly(copper phthalocyanine) are highly active while other metallophthalocyanines (Zn, Cu, Ni, Li) are nearly not active. Similarly, copper and cobalt hexadecafluorophthalocyanines show highly catalytic activity, but zinc hexadecafluorophthalocyanine is inactive. Moreover, iron phthalocya-nine chloride is also a good catalyst while nickel phthalocyanine-tetrasulfonic acid tetrasodium is a poor catalyst. Copper hexadecafluorophthalocyanine incorporated into hollow silica exhibits much better catalytic activity than bulk copper hexadecafluorophthalocyanine. This supported catalyst also gives a stable conversion until the fourth cycle of reaction.
Keywords:Epoxidation;Phthalocyanine;Metallophthalocyanines;Metallohexadecafluorophthalocyanines;Hollow silica
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