화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.40, 62-71, August, 2016
DOI10.1016/j.jiec.2016.06.007  Export Citation
Production of γ-valerolactone from furfural by a single-step process using Sn-Al-Beta zeolites: Optimizing the catalyst acid properties and process conditions
Haryo Pandu Winoto1, 2, Byoung Sung Ahn1, 2, and Jungho Jae1, 2, †
  • 1Clean Energy Research Center, Korea Institute of Science and Technology, 5 Hwarang-ro 14 gil, Seongbuk-gu, Seoul 02792, Republic of Korea
  • 2Department of Clean Energy and Chemical Engineering, Korea University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Republic of Korea
E-mail:
A bifunctional Sn-Al-Beta zeolite which possesses isolated Lewis and Brønsted acid sites was prepared by a post-synthesis procedure and applied to the one-pot conversion of furfural to γ-valerolactone (GVL), a value-added chemical. Sn-Al-Beta was capable of catalyzing a cascade of the transfer hydrogenation and hydrolysis of furfural to GVL by the interplay of Lewis and Brønsted acid sites. The degree of dealumination and the tin-incorporation method largely influence the acid properties of the catalyst and the catalyst selectivity. A high yield of GVL up to 60% was obtained with Sn-Al-Beta 7 (Si/Sn = 63 and Si/Al = 473) at 180 ℃ in 2-butanol.
Keywords:Biomass conversion;Bifunctional catalysis;Sn-Al-Beta zeolites;Furfural;γ-Valerolactone
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