The angular dependences of concentration broadening of EPR spectra for nitroxide spin probes in liquid crystals were experimentally measured. The obvious angular dependence of the broadening found for oriented smectic liquid crystal HOPDOB proves the paired localization of the probe molecules. The numerical calculation of the angular dependence taking into account the magnetic dipolar and spin exchange interactions have been used for quantitative determination of position of probes in the pairs. The probable localization of the probes in the smectic layer is discussed. (C) 2016 Elsevier B.V. All rights reserved.