Chemical Physics Letters, Vol.658, 309-314, 2016
Photocatalytic reduction of CO2 by CuxO nanocluster loaded SrTiO3 nanorod thin film
Photocatalytic carbon dioxide (CO2) conversion into carbon monoxide (CO) using H2O as an electron donor was achieved by the strontium titanate (SrTiO3: STO) nanorod thin films loaded with amorphous copper oxide (CuxO) nanoclusters. The loading of the CuxO-cocatalysts onto STO nanorods clearly improved the photocatalytic activity compared to bare STO nanorods. The CuxO-cocatalysts are composed of abundant and non-toxic elements, and can be loaded by using a simple and economical method. Our findings demonstrate that CuxO nanoclusters function as a general cocatalyst and can be used in combination with various semiconductors to construct low-cost and efficient photocatalytic CO2 reduction systems. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Photocatalyst;Nanorods;Cocatalyst;CuxO nanocluster;Impregnation method;CO2 reduction;Ubiquitous elements;ESR analysis;Isotope labeling analysis