화학공학소재연구정보센터
Chemical Physics Letters, Vol.659, 40-42, 2016
The viscosity and electrical conductivity of single molten salts
In addition to the well-established Arrhenius-type temperature-dependence of the specific and molar conductivities of molten salts, it turns out that they also depend linearly on the molar volumes, in analogy with the behavior of their fluidities. Similar values of the molar volumes representing the immobilization of the ions result from both kinds of flow phenomena. However, the activation energy for the fluidity is some five times larger than for the conductivity. (C) 2016 Elsevier B.V. All rights reserved.